In the IR spectra of the silica and silicate glasses, the shifts of the maximum intensity position of the mSi-O-Si, as band upon heating or applying mechanical stress could be attributed to changes in the distribution of bond parameters such as bond length and bond angle. Upon heating, isotropic expansion occurs and the density changes; upon applying mechanical stress, anisotropic strain is induced and a significant change in the Si-O-Si bond angle is observed. From molecular dynamics simulations of a silica glass, we show that the peak position shift correlates better with the asymmetric change in the Si-O bond length distribution, rather than the Si-O-Si bridge angle, the O-Si-O tetrahedral angle, or the density change. This new finding provides an insight into how and why the mSi-O-Si, as IR peak of soda lime silica (SLS) glass shifts upon chemical strengthening via ion exchange and thermal tempering.