Journal of Physical Chemistry B, Vol.101, No.32, 6271-6275, 1997
Uptake and Interaction of HI on Ice Films
The uptake of HI and co-uptake of HI + HCl on water-ice have been studied in a flow reactor at polar stratospheric temperature. The uptake of HI on ice is determined to be in the range of 1.1 x 10(14)-1.8 x 10(16) molecules/cm(2). The HI uptake thermodynamics is also investigated. The nature of higher uptake and the effect of acidity on the HX uptake are studied and discussed. The HI + HCl co-uptake experiment reveals that the uptake of HI on ice is about a factor of 10 more efficient than that of HCl at 188 K.
Keywords:NITRIC-ACID;VAPOR-PRESSURES;STRATOSPHERIC CLOUDS;WATER-ICE;DOPED ICE;HCL;SOLUBILITY;HBR;OZONE