Fe3O4 nanoparticle with magnetic properties and nanoscale features has provoked wide research interest and great potential application. Herein, a modified Stober and template-removing method was adopted to prepare magnetic mesoporous silica nanoparticles (MSNs), comprising a Fe3O4 core and a mesoporous silica shell. The shell was functionalized by amino-groups with tunable removal efficiency for aqueous heavy metals ions. Structural and magnetic properties were characterized by XRD, SEM, FT-IR, vibrating sample magnetometer (VSM) and BET (Brunauer-Emmertt-Teller) techniques. Also, the adsorbing efficiency for heavy metal ions was measured by UV-vis spectrometry. Results revealed that the pure magnetite is cubic with a side length of 40 - 70 nm, while the silica-coated magnetite is spherical with a diameter of 220-260 nm. The mesoporous silica shell has an average pore size of 2.6 nm and a high surface area of 675 m(2).g(-1), which lead to a large adsorption capacity for Fe3+ (up to 20.66 mg of Fe per g of adsorbent). Moreover, rapid magnetic separation and regeneration of as-prepared adsorbent were achieved conveniently. The distinctive structure and the heavy metal ions removal property of magnetic nanocomposites reflect their prospective application in water treatment. (C) 2017 Elsevier B.V. All rights reserved.