Journal of Physical Chemistry B, Vol.101, No.23, 4583-4587, 1997
Diffusion at Ultramicroelectrodes - Chronoamperometric Current Response Using Pade-Approximation
The analysis of transient chronoamperometric current response for various ultramicroelectrode geometries is carried out by solving the mixed boundary value problem for short and long time regimes. A two-point Pade approximant valid for entire time domain is developed. Tabular compilations of dimensionless current for ring and disc electrodes are reported.