The carbothermic reduction behavior of original ilmenite and pre-oxidized ilmenite concentrates were investigated by a non-isothermal method using a thermogravimetry facility. The reaction degree was calculated using the tail gas composition and the Starink method to analyze the activation energy of the reduction. The results demonstrated that trends of different reaction degree curves are similar under the same conditions. The average activation energy of the pre-oxidized ilmenite concentrate was less than that of the original form by approximately 25%, and the starting reduction temperature was lower by 67 K than that of the original ilmenite concentrate. However, the reduction time of the pre-oxidized ilmenite concentrate was longer than that of the original ilmenite concentrate for the same reaction degree; therefore, a slow reduction rate for the oxidization sample was observed. X-ray diffraction (XRD), scanning electron microscopy (SEM), and energy dispersion spectroscopy (EDS) were used to characterize the phase and micro-morphology of the two raw materials and compare the reduction products. (C) 2017 Elsevier B.V. All rights reserved.