Developing the structural diversity of microporous zeolitic frameworks, with integrated semiconducting properties is promising but remains a challenge. Reported here are two unique crystalline semiconductor zeolite analogues constructed from two kinds of indium selenide clusters with augmented ctn and zeolite-type sod networks. The intrinsic semiconducting nature in these In Se domains gives rise to pore-size dependent and visible-light-driven photo catalytic activity for organic dye degradation.