화학공학소재연구정보센터
Industrial & Engineering Chemistry Research, Vol.56, No.46, 13743-13750, 2017
Cross-Linked Polyamides Synthesized through a Michael Addition Reaction Coupled with Bulk Polycondensation
A simple route is described to synthesize cross linked polyamides (cPAs) with excellent mechanical properties at mild conditions through a Michael addition reaction coupled with bulk polycondensation. A Michael addition of methyl acrylate with 1,6-hexanediamine was conducted in a bulk state at a N-H/C=C molar ratio of 1:1 under normal pressure at 50 degrees C, and a hexanediamine-tetraester was prepared. Bulk polycondensation of the hexanediamine-tetraester with 1,6-hexanediamine and isophoronediamine was conducted at 170 degrees C for 1 h and then in tetrafluoroethylene mold under reduced pressure for another 8 h. A series of cPA films were prepared. The Michael addition and the polycondensation were monitored by Fourier transform infrared, H-1 NMR, and electrospray ionization mass spectrometry spectra. The cPA films were characterized with differential scanning calorimetry, thermogravimetric analysis, dynamic mechanical analysis, and a tensile test. These cPAs exhibited T-g ranging from 37 to 61 degrees C, tensile strength up to 71 MPa, and strain at break of about 11%.