It is well known that high performance supercapacitor with high energy and power density is usually degrade at high temperatures. Therefore, to explore the thermal stability, temperature dependent study of supercapacitor is very useful. In the present work, La2O3 nanosheet decorated reduce graphene oxide is synthesized to use it as electrode material in high performance supercapacitor. Temperature dependent electrochemical behavior viz. charging discharging and current voltage (I-V) characteristics are studied to explore the thermal stability of the system. In comparison to pristine rGO, the specific capacitance of La2O3 decorated sample is found to increase by 158% at temperatures 30 degrees C and 205% at 70 degrees C respectively. The highest value obtained is 751 F/g at temperature 70 degrees C at a current density of 1 A/g. Remarkably the specific capacitance of hybrid electrode retains 78% of its original value at temperature 30 degrees C; conversely 67% of its original value even at higher temperature 70 degrees C after 2000 cycles. The enhancement of specific capacitance is explained by the charge transfer effect between rGO and La2O3 at the interface. (c) 2017 Elsevier Ltd. All rights reserved.