Colorimetric properties of fluorescent materials depend on the SPD of the illumination. That is why most standards for evaluating them specify the illuminations, which are often hard-to-realize daylight illuminants. The presented method using commercially available LEDs enables accurate enough colorimetric measurements of FWA-treated papers or prints on them illuminated by the specified illuminant. The total spectral radiance factor of a fluorescent specimen, from which most colorimetric values are derived, consists of the luminescent spectral radiance factor and the spectral reflectance factor. This method separately estimates those of FWA-treated paper to add up to the total spectral radiance factor. The luminescent spectral radiance factor is obtained by estimating the SPD of luminescence excited by the specified illuminant as the weighted sum of the multiple SPDs of luminescence excited by the respective narrow band LED emissions at different wavelengths. The LEDs and their weights are determined optimally for generally used papers. The spectral reflectance factor is derived from the estimated SPD of the radiation with fluorescence excluded from the paper illuminated by visible illumination. The method was applied with five different illumination systems each using two or three narrow band LEDs in the excitation range. They were evaluated by measuring the total spectral radiance factors by D50 of seven FWA-treated papers and CMYK prints on four papers. The derived colorimetric values were compared to the respective references by the ideal D50.