Herein, the multiporous MnO/N-doped carbon (MnO/NC) composite based on the abundant and inexpensive electrolytic manganese dioxide were fabricated through a facile microwave-assisted carbonthermal reduction, combined with a subsequent in-situ polymerization of polydopamine onto MnO along with thermal treatment. As an anode material, it retains a reversible capacity of 770.5 mAh g(-1) at 300 mA g(-1) and high Coulombic efficiency of 99% over 500 cycles, superior than those values of the pure multiporous MnO alone. The impressive performance is attributed to the splendid structure stability contributed by well-connected three-dimensional porous configuration and the enhanced reaction kinetics as well as electrical conductivity incurred by N-doped carbon layer with multiple type nitrogen.