Purolite AC-20 and Norit RB 0.8CC activated carbons impregnated with AgNO3 were used for the removal of CN- and Ag-CN complex from model wastewater. The formed Ag-0 centers were approved by scanning electron microscopy micrographs and X-ray powder diffraction data. The degree of Ag-0 participating in CN- sorption varied from 100 to 45% on AC-20/Ag and from 100 to 73% on RB 0.8CC/Ag, by varying [CN-]/[Ag] in the initial solution from 2.0 to 19.2. The Freundlich isotherm and Fleming kinetic models were consistent with the experimental data. The K-F values for the CN- adsorption on AC-20/Ag and RB 0.8CC/Ag increased by a factor of 1.2 and 1.5, but they lowered for Ag-CN adsorption by a factor of 4.1 and 2.1, respectively, as compared to that of plain activated carbons. The removal of 90% cyanides is appropriate by combining two batches from activated carbon: impregnated, mainly for the removal of CN-, and plain, removing the rest of Ag-CN.