Investigating the inherent wettability of rock surfaces at nanoscale is of great importance in ore floatation and oil recovery field. Using molecular dynamics simulations, we systematically study the wetting behavior of water on different rock surfaces (silica, calcite, gypsum, halite and graphite) at nanoscale. It is demonstrated that the inherent rock wettability follows the order of gypsum > calcite > halite > silica > graphite. Remarkably, we also manifest that the polarity of oil molecules can affect the water contact angles on silica surface. For example, the water contact angles on silica surface in hexane, dodecane, thiophene and toluene are 58 +/- 2 degrees, 63 +/- 3 degrees, 90 +/- 1 degrees, 118 +/- 1 degrees, respectively. Furthermore, we investigate the wetting behavior of water on heterogeneous rock surfaces and find that water molecules can move from hydrophobic surface to hydrophilic surface. (C) 2017 Elsevier B.V. All rights reserved.