화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Macromolecular Research, Vol.26, No.1, 77-84, January, 2018
DOI10.1007/s13233-018-6009-0  Export Citation
Effect of oxygen functionalities of graphene oxide on polymerization and thermal properties of reactive benzoxazine nanocomposites
Wenkai Zhang, Yanshan Zhan, Xiuxiu Gao, Runming Li, Weiwei Zhu, Hao Xu, Baoying Liu, Xiaomin Fang†, Yuanqing Xu, and Tao Ding†
  • Institute of Fine Chemistry and Engineering, Henan Engineering Laboratory of Flame-Retardant and Functional Materials, College of Chemistry and Chemical Engineering, Henan University, Kaifeng 475004, P. R. China
E-mail:,
Herein, we report the effect of oxygen functionalities of graphene oxide on thermal activated polymerization and thermal properties of reactive benzoxazine nanocomposites. The numbers of oxygen moieties of graphene oxide (GO) are controlled by hydrothermal reduction. The polymerization behavior of benzoxazine monomer (BA-a) is studied by Fourier transform infrared spectroscopy, differential scanning calorimetry and rheological analysis. It is hypothesized that the GO not only exhibits accelerated effect on the polymerization of the BA-a, but also the oxygen moieties such as carboxyl groups of GO interact with the benzoxazine polymers, leading to several orders of magnitude increase in the chemoviscosity and modulus of composite system. Thermal conductivity of poly(BA-a)/GO composite increases from an initial value of ∼0.27 W/mK to 0.47 W/mK as the loading increases from 1 wt% to 6 wt% (enhancement factor up to 176%). Moreover, the nanocomposites display enhanced initial decomposition temperature and char yields as the degree of GO reduction increases.
Keywords:benzoxazine;graphene oxide;oxygen functionalities;polymerization;thermal conductivity;thermal stability
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