Enhanced phosphorus bioavailability and heavy metal removal from sewage sludge ash through thermochemical treatment with chlorine donors

Seulki Jeon; Dong-Jin Kim

Journal of Industrial and Engineering Chemistry, Vol.58, 216-221, February, 2018

DOI10.1016/j.jiec.2017.09.028 Export Citation

Enhanced phosphorus bioavailability and heavy metal removal from sewage sludge ash through thermochemical treatment with chlorine donors

Seulki Jeon, and Dong-Jin Kim^†

Department of Environmental Sciences and Biotechnology & Institute of Energy and Environment, Hallym University, Chuncheon, Gangwon 24252, Republic of Korea

E-mail:

Direct application of sewage sludge ash (SSA) to agriculture is mostly prohibited due to its heavy metals and limited bioavailability. Thermochemical treatment of SSA with Cl-donors were carried out to remove heavy metals and enhance P bioavailability. MgCl2 and CaCl2 removed more heavy metal than other Cl-donors. Pb was completely removed followed by Cd, Zn, Cu. They also increased P bioavailability by the conversion of Al?P to Ca/Mg-P which was confirmed by chemical fractionation. XRD confirmed the conversion of AlPO4 to Ca5(PO4)3Cl, Ca3(PO4)2, and Mg3(PO4)2 by the thermochemical treatment.

Keywords:Bioavailability;Cl-donor;Phosphorus recovery;Sewage sludge ash;Thermochemical treatment

[References]

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Ali TU, Kim DJ, Bioresour. Technol., 217, 233 (2016)
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[Referenced By]

[1] Donatello S, Cheeseman CR, Waste Manage., 33, 2329 (2013)

[2] Kim M, Han DW, Kim DJ, Bioresour. Technol., 190, 522 (2015)

[3] Ali TU, Kim DJ, Bioresour. Technol., 217, 233 (2016)

[4] Liu Z, Qian G, Sun Y, Xu R, Zhou J, Xu Y, Energy Fuels, 24, 2470 (2010)

[5] Lim BH, Kim DJ, J. Ind. Eng. Chem., 46, 62 (2017)

[6] Chris Y, Kirk D W, J. Hazard. Mater., 64, 75 (1999)

[7] Han J, Xu M, Yao H, Furuuchi M, Sakano T, Kim HJ, Waste Manage., 27, 833 (2008)

[8] Adam C, Peplinski B, Michaelis M, Kley G, Simon FG, Waste Manage., 29, 1122 (2009)

[9] Vogel C, Adam C, Environ. Sci. Technol., 45, 7445 (2011)

[10] Anderson KJ, Kisser MI, Digestion of Solid Matrices.Desk Study Horizontal, Eurofins A/A, Austria, 2004.

[11] APHA, AWWA, WEF, Standard Methods for the Examination of Water and Wastewater, 18th ed., (2005).

[12] European Parliament, Council of the European Union. Regulation (EC) No 2003/2003 of the European Parliament and of the Council of 13 October 2003 relating to fertilisers, 2003. http://data.europa.eu/eli/reg/2003/2003/oj.

[13] Paludan C, Jensen HS, Wetlands, 15, 365 (1995)

[14] Mattenberger H, Fraissler G, Brunner T, Herk P, Hermann L, Obernberger I, Waste Manage., 28, 2709 (2008)

[15] Nowak B, Rocha SF, Aschenbrenner P, Rechberger H, Winter F, Chem. Eng. J., 179, 178 (2012)

[16] Nowak B, Perutka L, Aschenbrenner P, Kraus P, Rechberger H, Waste Manage., 31, 1285 (2011)

[17] Li RD, Zhao WW, Li YL, Wang WY, Zhu X, J. Hazard. Mater., 283, 423 (2015)

[18] Fraissler G, Joller M, Mattenberger H, Brunner T, Obernberger I, Chem. Eng. Process., 48(1), 152 (2009)

[19] Zhang YG, Chen Y, Meng AH, Li QH, Cheng HF, J. Hazard. Mater., 153(1-2), 309 (2008)

[20] Perry RH, Green DW, Maloney JO, Perry’s Chemical Engineers’ Handbook, 6th ed., McGraw-Hill, New York, 1985.

[21] Yaws CL, The Yaws Handbook of Vapor Pressure: Antoine Coefficients, 2nd ed., Gulf Professional Publishing, Texas, 2015.

[22] Dean JA, Lange’s Handbook of Chemistry, 12th ed., McGraw-Hill, New York, 1979.

[23] Peplinski B, Adam C, Michaelis M, Kley G, Emmerling F, Simon FG, Kristallogr Z, Suppl., 30, 459 (2009)

[24] Lee MS, Kim DJ, J. Ind. Eng. Chem., 51, 64 (2017)

[25] Gustafsson JP, Visual MINTEQ. Ver. 3.0, 2012. http://vminteq.lwr.kth.se/.