Journal of Industrial and Engineering Chemistry, Vol.58, 179-188, February, 2018
Excellent anti-fouling performance of PVDF polymeric membrane modified by enhanced CaA gel-layer
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Calcium alginate gel-layer polymeric membranes with excellent anti-fouling ability were developed via dip-coating method through sodium alginate and calcium chloride to form gel-layers onto different polyvinylidene fluoride membranes. SEM, FT-IR, DCA and mechanical properties were operated for characterization. Comprehensive investigation of anti-fouling ability including PWF, FRR%, long-term performances with fouling resistances were conducted. Results showed a significant improvement after cross-linking, in which recovery rate reached to 99.2% and kept steady while contact angle decreased remarkably. Enhanced gel-layer with MWCNTs-COOH was also developed and applied in the commercial PVDF MF membrane and applied in fresh milk emulsion concentration.
Keywords:Calcium alginate (CaA);Gel-layer membrane;Anti-fouling ability;Polyvinylidene fluoride (PVDF);Dip-coating
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