Oxalate formation during hydrogen peroxide-reinforced oxygen delignification

Yingying Liu; Shujuan Ge; Youming Li; Bingyun Li; Hailong Li

Journal of Industrial and Engineering Chemistry, Vol.58, 45-50, February, 2018

DOI10.1016/j.jiec.2017.09.005 Export Citation

Oxalate formation during hydrogen peroxide-reinforced oxygen delignification

Yingying Liu, Shujuan Ge, Youming Li, Bingyun Li, and Hailong Li^†

State Key Laboratory of Pulp and Paper Engineering, South China University of Technology, Guangzhou, 510640, China

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The effects of different process parameters (alkali dosage, hydrogen peroxide dosage, temperature, reaction time, and oxygen pressure) on oxalate formation during hydrogen peroxide-reinforced oxygen delignification (OP) of Eucalyptus kraft pulp were investigated in the present study. The relationships between oxalate formation and the dosages of both alkali and peroxide were found to be almost linear. Oxalate formation could be divided into “fast” and “slow” periods, depending on the reaction time. The best selectivity for the OP process was achieved using an alkali dosage of 2.0%, a hydrogen peroxide dosage of 2.0%, a temperature of 100 °C, an oxygen pressure of 0.6 MPa and a reaction time of 60 min. Oxalate formation was also, to some extent, reduced under these conditions. These results will be very helpful in optimizing the OP process, controlling oxalate formation and improving product quality.

Keywords:Oxalate;Hydrogen peroxide-reinforced oxygen delignification;Control;Kappa number;Viscosity

[References]

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[2] Fang LP, Zheng MH, Liu GR, Zhao YY, Liu WB, Huang LY, Guo L, Chemosphere, 168, 523 (2017)

[3] Han S, Liu W, Wu S, Long Z, Hou Q, J. Ind. Eng. Chem., 21, 121 (2015)

[4] Lacorte S, Latorre A, Barcelo D, Rigol A, Malmqvist A, Welander T, Trends Anal. Chem., 22, 725 (2003)

[5] Bouiri B, Amrani M, J. Ind. Eng. Chem., 16(4), 587 (2010)

[6] Leigh JK, Rajput J, Richardson DE, Inorg. Chem., 53(13), 6715 (2014)

[7] Asghari I, Mousavi SM, Amiri F, Tavassoli S, J. Ind. Eng. Chem., 19(4), 1069 (2013)

[8] Pouran SR, Aziz ARA, Daud WMAW, J. Ind. Eng. Chem., 21, 53 (2015)

[9] Li J, Zhang CY, Hu HC, Chai XS, Bioresour. Technol., 202, 119 (2016)

[10] Jafari V, Sixta H, van Heiningen A, Ind. Eng. Chem. Res., 53(20), 8385 (2014)

[11] Yang R, Lucia L, Ragauskas AJ, Jameel H, J. Wood Chem. Technol., 23, 13 (2003)

[12] Collins TJ, Acc. Chem. Res., 35, 782 (2002)

[13] Parthasarathy VR, Klein R, TAPPI J., 73, 177 (1990)

[14] Li HL, Chai XS, DeMartini N, J. Wood Chem. Technol., 32, 187 (2012)

[15] Yu L, Ni YH, J. Tech. Assoc. Aus. Nz. Pulp Pap. Ind., 58, 138 (2005)

[16] Duong TD, Hoang M, Nguyen ML, J. Colloid Interface Sci., 287(2), 438 (2005)

[17] Elfil H, Roques H, Desalination, 137(1-3), 177 (2001)

[18] Haara M, Sundberg A, Willfor S, Nord. Pulp Paper Res J, 26, 263 (2011)

[19] Tunik L, Furedi-Milhofer H, Garti N, Langmuir, 14(12), 3351 (1998)

[20] Hasson D, Shemer H, Sher A, Ind. Eng. Chem. Res., 50(12), 7601 (2011)

[21] Li HL, DeMartini N, Chai XS, Ind. Eng. Chem. Res., 53(44), 17282 (2014)

[22] Krasowski JA, Marton J, J. Wood Chem. Technol., 3, 445 (1983)

[23] Zhao H, Hou Q, Hong Y, Liu W, Li Y, Tong F, J. Ind. Eng. Chem., 20(4), 1571 (2014)

[24] Huber P, Burnet A, Petit-Conil M, J. Environ. Manage., 141, 36 (2014)

[25] Huber P, Nivelon S, Nortier P, TAPPI J., 11, 53 (2012)

[26] He Z, Yang Y, Ni YH, J. Pulp Pap. Sci., 34, 153 (2008)

[27] Zhang JX, Yu L, Ni YH, Zhou Y, Joliette D, Pulp Pap. Can., 107, 52 (2006)

[28] Yu L, Ni Y, Pulp Pap. Can. Ont., 108, 39 (2007)

[29] Bailey CW, Diss. Abstr. Int. Sect. B (1969).

[30] Hu HC, Jin HJ, Chai XS, J. Ind. Eng. Chem., 20(1), 13 (2014)

[31] Chai XS, Samp J, Song HN, Zhu HX, J. Chromatogr. A, 1112, 209 (2006)

[32] Li HL, Chai XS, DeMartini N, Zhan HY, Fu SY, J. Chromatogr. A, 1192, 208 (2008)

[33] Hu HC, Tian YX, Chai XS, Si WF, Chen G, J. Ind. Eng. Chem., 19(3), 748 (2013)

[34] Li HL, Liu YY, Zhang Q, Zhan HY, Anal. Methods, 6, 3720 (2014)

[35] Fu SY, Lucia LA, Ind. Eng. Chem. Res., 42(19), 4269 (2003)

[36] Vu THM, Pakkanen H, Alen R, Ind. Crop. Prod., 19, 49 (2004)

[37] Ji Y, Vanska E, Heiningen AV, Holzforschung, 63, 264 (2009)

[38] Haara M, Pranovich A, Sundberg A, Willfor S, Holzforschung, 68, 393 (2014)

[39] He Z, Ni Y, Zhang E, J. Pulp Pap. Sci., 29, 391 (2003)

[40] Anipsitakis GP, Dionysiou DD, Environ. Sci. Technol., 38, 3705 (2004)

[41] Vanska E, Vihela T, Peresin MS, Vartiainen J, Hummel M, Vuorinen T, Cellulose, 23, 199 (2016)

[42] Neyens E, Baeyens J, J. Hazard. Mater., 98(1-3), 33 (2003)