TiO2 나노입자를 이용한 고인장 PVC 필름 제조

엄원식; 김영배; 김성훈; 한태희; Wonsik Eom; Young Bae Kim; Seong Hun Kim; Tae Hee Han

Polymer(Korea), Vol.41, No.6, 992-997, November, 2017

DOI10.7317/pk.2017.41.6.992 Export Citation

TiO2 나노입자를 이용한 고인장 PVC 필름 제조

High-Strain PVC Film Plasticized by TiO2 Nanoparticles

엄원식, 김영배, 김성훈^†, 한태희^†

한양대학교 유기나노공학과

Wonsik Eom, Young Bae Kim, Seong Hun Kim^†, and Tae Hee Han^†

Department of Organic and Nano Engineering, Hanyang University, Seoul 04763, Korea

E-mail:,

초록

Tetrahydrofuran(THF)를 이용하여 제조한 poly(vinyl chloride)(PVC) 필름의 낮은 인장률과 인성이 TiO2 나노입자를 0.8 wt% 미만의 농도로 첨가하였을 때 향상되었다. 제조된 PVC/TiO2 복합재료는 383%의 우수한 인장률과 64.7 J m-3의 인성을 나타냈는데, 이는 PVC 고분자 사슬과 나노입자 사이에서 분자간 인력이 작용하기 때문이다.

The low strain and toughness of tetrahydrofuran (THF)-cast poly(vinyl chloride) (PVC) film were mitigated by introducing TiO2 nanoparticles at loading below 0.8 wt%. The thus obtained PVC/TiO2 composite showed superb elongation at break (383%) and toughness (64.7 J m-3) due to modified molecular interactions between nanoparticles and PVC chains.

Keywords:poly(vinyl chloride);TiO2;inorganic nanofiller;high strain

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[2] Hu JM, Jia X, Li CH, Ma ZY, Zhang GX, Sheng WB, Zhang XL, Wei Z, J. Mater. Sci., 49(7), 2943 (2014)

[3] Li KW, JCIIE, 20, 472 (2003)

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[5] Fried JR, Polymer science and technology, 2nd edition, Prentice Hall, Vicksburg, 2014.

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[8] Tickner JA, Schettler T, Guidotti T, McCally M, Rossi M, Am. J. Ind. Med., 39, 100 (2001)

[9] Moghbeli MR, Tolue S, J. Appl. Polym. Sci., 113(4), 2590 (2009)

[10] Yin B, Hakkarainen M, J. Mater. Chem., 21, 8670 (2011)

[11] Yao K, Gong J, Tian N, Lin Y, Wen X, Jiang Z, Na H, Tang T, RSC Adv., 5, 31910 (2015)

[12] Hosseini SM, Askari M, Koranian P, Madaeni SS, Moghadassi AR, J. Ind. Eng. Chem., 20(4), 2510 (2014)

[13] Liu J, Yan H, Jiang K, Ceram. Int., 39, 6215 (2013)

[14] Xie XL, Liu QX, Li RKY, Zhou XP, Zhang QX, Yu ZZ, Mai YW, Polymer, 45(19), 6665 (2004)

[15] Horikoshi S, Serpone N, Hisamatsu Y, Hidaka H, Environ. Sci. Technol., 32, 4010 (1998)

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[18] Calo E, Greco A, Maffezzoli A, Polym. Degrad. Stabil., 96, 784 (2011)

[19] Nakajima N, Sadeghi M, Kyu T, J. Appl. Polym. Sci., 41, 889 (1990)

[20] Wan CY, Qiao XY, Zhang Y, Zhang YX, J. Appl. Polym. Sci., 89(8), 2184 (2003)

[21] Da Silva MA, Vieira MGA, Macumoto ACG, Beppu MM, Polym. Test, 30, 478 (2011)

[22] Hasan M, Lee M, Prog. Nat. Sci., 24, 579 (2014)

[23] Chen JL, Xue G, Li YH, Wang L, Tian GH, Macromolecules, 34(5), 1297 (2001)

[24] Gupta SM, Tripathi M, Chin. Sci. Bull., 56, 1639 (2011)

[25] Lee S, Park H, Paik U, Han TH, J. Solid State Chem., 224, 76 (2015)

[26] Fryer DS, Peters RD, Kim EJ, Tomaszewski JE, de Pablo JJ, Nealey PF, White CC, Wu WL, Macromolecules, 34(16), 5627 (2001)

[27] Mali SS, Betty CA, Bhosale PN, Patil P, ECS J. Solid State Sci. Technol., 1, M15 (2012)

[28] Cho S, Choi W, J. Photochem. Photobiol. A-Chem., 143, 221 (2001)

[29] Matsuzawa S, Maneerat C, Hayata Y, Hirakawa T, Negishi N, Sano T, Appl. Catal. B: Environ., 83(1-2), 39 (2008)

[30] Park H, Choi WY, J. Phys. Chem. B, 108(13), 4086 (2004)

[31] Wu DZ, Wang XD, Song YZ, Jin RG, J. Appl. Polym. Sci., 92(4), 2714 (2004)

[32] Zuiderduin WCJ, Westzaan C, Huetink J, Gaymans RJ, Polymer, 44(1), 261 (2003)

[33] Thio YS, Argon AS, Cohen RE, Weinberg M, Polymer, 43(13), 3661 (2002)

[34] Wang Z, Liu J, Wu S, Wang W, Zhang L, Phys. Chem. Chem. Phys., 12, 3014 (2010)

[35] Barrau S, Demont P, Maraval C, Bernes A, Lacabanne C, Macromol. Rapid Commun., 26(5), 390 (2005)