화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.56, 1-34, December, 2017
DOI10.1016/j.jiec.2017.06.049  Export Citation
A review on reactivity and stability of heterogeneous metal catalysts for deoxygenation of bio-oil model compounds
Andrew Ng Kay Lup1, Faisal Abnisa1, 2, Wan Mohd Ashri Wan Daud1, †, and Mohamed Kheireddine Aroua3
  • 1Department of Chemical Engineering, Faculty of Engineering, University of Malaya, 50603, Kuala Lumpur, Malaysia
  • 2Department of Chemical Engineering, Faculty of Engineering, University of Malikussaleh, Lhokseumawe 24351, Indonesia
  • 3School of Science and Technology, Sunway University, No.5 Jalan Universiti, 47500 Selangor Darul Ehsan, Malaysia
E-mail:
Catalytic deoxygenation is a fundamental process for bio-oil upgrading due to its high oxygen content which will result in lower heating value, corrosion and instability issues. The discovery of an excellent heterogeneous deoxygenation metal catalyst with high deoxygenation activity is a necessary breakthrough for an optimized bio-oil catalytic deoxygenation. For an effective deoxygenation supported metal catalyst, properties such as high H2 sticking coefficient, optimal metal-oxygen bond strength and suitable acid strength from support are needed to ensure facile scission of C- O bonds and activation of H2 and O-containing compounds. Metals such as Fe, Ru, Sn, W, Zr and supports such as C, TiO2, ZrO2 which are oxophilic were also observed to enhance direct removal of oxygen from O-containing compounds due to their high C - O and C = O bond affinities. The choice of support is important to ensure it has optimal physicochemical properties for facile deoxygenation and the optimal acid strength to enhance C - O hydrogenolysis activity while minimizing coke formation. The choice of metal is dependent on the type of model compound since different metals catalyze different reaction pathways of the deoxygenation of model compounds. This review presents on the use of heterogeneous metal catalysts in the deoxygenation of bio-oil model compounds through several perspectives which are catalytic properties, reaction conditions, deactivation and regeneration of metal catalysts. In addition, several outlooks on the feasible range of reaction condition for catalytic deoxygenation and criteria of excellent deoxygenation supported metal catalysts were also expressed in this article based on the studies on the literatures.
Keywords:Bio-oil;Metal catalyst;Deoxygenation;Catalytic deactivation;Catalytic regeneration
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