화학공학소재연구정보센터
Nature Materials, Vol.16, No.10, 987-+, 2017
Bronze-mean hexagonal quasicrystal
The most striking feature of conventional quasicrystals is their non-traditional symmetry characterized by icosahedral, dodecagonal, decagonal or octagonal axes(1-6). The symmetry and the aperiodicity of these materials stem from an irrational ratio of two or more length scales controlling their structure, the best-known examples being the Penrose(7,8) and the Ammann-Beenker(9,10) tiling as two-dimensional models related to the golden and the silver mean, respectively. Surprisingly, no other metallic-mean tilings have been discovered so far. Here we propose a self-similar bronze-mean hexagonal pattern, which may be viewed as a projection of a higher-dimensional periodic lattice with a Koch-like snowflake projection window. We use numerical simulations todemonstrate that a disordered variant(11) of this quasicrystal can be materialized in soft polymeric colloidal particles with a core-shell architecture(12-17). Moreover, by varying the geometry of the pattern we generate a continuous sequence of structures, which provide an alternative interpretation of quasicrystalline approximants observed in several metal-silicon alloys(18).