Langmuir, Vol.33, No.38, 9972-9978, 2017
Self-Healing Superhydrophobic Materials Showing Quick Damage Recovery and Long-Term Durability
Superhydrophobic coatings/materials are important for a wide variety of applications, but the majority of these manmade coatings/materials still suffer from poor durability because of their lack of self-healing ability. Here, we report novel super hydrophobic materials which can quickly self-heal from various severe types of damage. In this study, we used poly(dimettrylsiloxane) (PDMS) infused with two liquids: trichloropropylsilane, which reacts with ambient moisture to self-assemble into grass-like microfibers (named silicone micro/nanograss) on the surfaces and low-viscosity silicone oil (SO), which remains within the PDMS matrices and acts as a self-healing agent. Because of the silicone micro/nanograss structures on the PDMS surfaces and the effective preserve/protection system of a large quantity of SO within the PDMS matrices, our superhydrophobic materials showed quick superhydrophobic recovery under ambient conditions (within 1-2 h) even after exposure to plasma (24 h), boiling water, chemicals, and outside environments. Such an ability is superior to the best self-healing superhydrophobic coatings/materials reported so far.