Efficient separation of photo-generated electrons and holes is a crucial aspect for photo catalytic hydrogen evolution. Herein, novel plate-like Co(OH)(2) decorated TiO2 nanosheets for photocatalytic water splitting were synthesized by a facile in-situ synthetic method. The results of X-ray diffractometry (XRD), transmission electron microscope (TEM), UV-Vis diffusion reflectance spectroscopy (DRS) and X-ray photoelectron spectroscopy (XPS) indicate the successfully incorporation of Co(OH)(2) co-catalysts onto the surface of TiO2 nanosheet photocatalysts. Further photocatalytic hydrogen evolution experiments illustrate that all Co(OH)(2) decorated TiO2 samples show higher rate of hydrogen production performance than pure TiO2 sample and the composite sample with Co(OH)(2) loading amount of 0.5mol% presents the highest photocatalytic hydrogen production activity of 746.93 mu mol g(-1).h(-1). It is indicated that plate-like Co(OH)(2) particle act as an electron collector, which leads to photo-generated electrons transfer from TiO2 to Co(OH)(2), and therefore enhance the photocatalytic activity. Based on above results, a possible mechanism is proposed and further verified by surface photovoltage spectra (SPV). (C) 2017 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.