The use of solar photovoltaic (PV) is universally considered valuable for its renewable and clean nature; solar energy is especially important in regions far from urban centers and power distribution networks. It is known that the loss due to the latitude and the atmospheric layer is partially offset in very different annual distribution (i.e., by the long summer days) and in sparsely populated areas, because of the clearer atmosphere. Even with these assumptions, low temperatures (snow often combined with strong winds) and the effects of seasonality are difficult obstacles for the proper use of solar PV energy at high latitudes. In this work, both analytical and experimental data of the solar resource at Esperanza Base, Antarctica, are presented. The PV modules were installed in a vertical configuration and NW NE orientation, which not only maximizes performance but also mitigates the adverse effects due to the latitude. In order to overcome the very asymmetric annual irradiance distribution, the use of a system of hydrogen production and accumulation, is proposed for effective energy storage. The results of two years of evaluation of PV potential at Esperanza Base show that duplicating the PV capture area in Esperanza allows to obtain the same total annual energy than the maximum acquired in Buenos Aires (PV module facing north with optimum tilt for solar capture). To effectively overcome discontinuity of solar energy and its sharp drop in four of the twelve months of the year an appropriate hydrogen vector system is proposed and analyzed. (C) 2017 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.