In this study, polybenzimidazole (PBI) is used as membrane material of the high temperature membrane electrode assembly which has the features of high-performance stability and high CO tolerance. Moreover, compared to graphite bipolar plates, metallic bipolar plates have better mechanical properties and seismic capacity, as well as lighter weight. We thus use metallic bipolar plates and a PBI-based membrane electrode assembly to setup a single cell and examine its performance. The experimental results show that the cell temperature has a significant effect on the cell performance. When the temperature increases from 120 degrees C to 180 degrees C, the performance is significantly enhanced. Moreover, the CO tolerance of the fuel cell increases along with the temperature. At the same time, methane is fed in the anode stream to assess the performance of the cell under different simulated methane reformate gases. The test of various CH4/H-2 mixtures reveals the residual methane in the reformate gases only decreases fuel cell performance slightly due to the dilution effect. We also examined H-2/CO/N-2/CH4 mixtures in this study, and these had only a small effect on the fuel cell performance at cell temperatures higher than 160 degrees C. As such, it is recommended that the cell temperature should be kept higher than 160 degrees C. (C) 2017 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.