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Journal of Physical Chemistry A, Vol.102, No.36, 7089-7092, 1998
An interesting isotope effect in the Raman excitation profile for HI
It is shown that the Raman excitation profile for the fundamental Stokes transition of DI in the vicinity of its electronic transition to the nearby dissociative states exhibits a larger deenhancement than that for HI, as a result of larger interference between the resonance Raman amplitudes for the four closely lying excited (dissociative) electronic states.