In oxy-fuel combustion, switching from nitrogen to carbon dioxide atmosphere with higher oxygen concentration will affect the oxidation rate of soot, and it was observed in our recent study on soot emission from biomass pyrolysis that potassium (K) crystals are embedded in soot and its precursor clusters. In this study, the effects of K-doping (KCI and K2SO4) and O-2 concentration on soot oxidation in O-2/CO2 atmosphere are studied using thermogravimetric analysis (TGA), and the extent of catalysis is compared with that in O-2/N-2 atmosphere. The delays on start, peak and end temperatures of soot oxidation are observed in O-2/CO2 atmosphere. However, increase in O-2 concentration which promotes oxidation significantly reduces the delay. All the K-doping cases results in accelerated soot oxidation rate, but catalytic role of the K-doping in O-2/CO2 is significantly lower than that in O-2/N-2 because the CO2-enriched environment inhibits the performance of potassium as oxygen carrier. The accelerating degree from K-doping is also affected by the potassium type, doping mass and oxygen concentration. KCl acts as a better, more efficient doping agent than K2SO4 with the increase in doping mass. The catalytic effect of K2SO4 will not change and even decrease at 375 p.mol(K)/g(soot) for K2SO4 while the catalytic role of KCl keeps increasing even at 600 tmol(K)/g(soot) for KCI. In O-2 concentration range of 5-30%, the accelerating degree from K-doping presents the minimum value around 15%. This phenomenon strongly approves the hypothesis that potassium as the oxygen carrier and accelerating the oxygen transportation, because in the cases of without K-doping and at a high O-2 concentration there is no additional active site for more O-2 adsorption thus inducing the slow accelerating degree. The kinetic analysis indicates the first order reaction for soot oxidation and also a good compensation relation between apparent activation energy E and logarithmic frequency factor A. E is generally reduced with the atmosphere changing from O-2/N-2 to O-2/CO2, with K-doping, and with O-2 concentration decreasing. This study is beneficial to demonstrate the mechanism of how potassium doping and oxygen concentration affect soot oxidation rate in oxy-fuel combustion environment. (C) 2017 Elsevier Ltd. All rights reserved.