Mass transfer from a bubble to the surrounding liquid plays an important role in industry processes. To improve the efficiency of the industrial processes, a deep understanding of the mass transfer mechanism is essential. In the present study, the relationship between the instantaneous mass transfer and the motions of the bubble and three-dimensional bubble wakes is discussed, on the basis of precise measurement. Moreover, since some industrial applications are contaminated system, the authors consider influences of bubble-surface contamination on the above. In the present experiments, purified water, and water contaminated with a very small amount of surfactant (1-pentanol) were employed. LIF (Laser Induced Fluorescence) technique and HPTS (a pH-sensitive dye) that was calibrated through a photoelectric optical fiber probe in advance were employed to visualize the mass transfer of the bubble and the wake structure of the bubble. The authors investigated highly reproducible single bubbles (considered to be almost the same bubble) launched from a special bubble-launch device; successfully they acquired pseudo-time-series sliced bubble wakes' images from every y-z plane at an equidistant interval. By processing the pseudo-time-series images through their own new image-processing, they challengingly reconstructed three-dimensional bubble wakes. From careful observations on the three-dimensional bubble wakes' structure, they indirectly found out that the Marangoni convection, which was induced by the non-uniform distribution of surfactants desorption on the bubble surface, raised changes in the boundary layers in the contaminated water. The authors discussed the influences of gas-liquid interface contamination on the bubble motions, bubble wakes, and mass transfer process based on the reconstruction of three-dimensional bubble wakes in the purified water and contaminated water. (C) 2017 Elsevier Ltd. All rights reserved.