To construct rapid C3H8 transport pathways in polymer matrix, alkyl chain-functionalized graphene oxide (GO) was prepared via grafting octadecylamine (ODA) molecules and then embedded into polydimethylsiloxane (PDMS) matrix to obtain high-efficiency mixed matrix membranes (MMMs). The incorporation of alkyl chains contributes to lowering the surface energy of GO nanosheets and providing higher affinity with PDMS matrix. Additionally, the alkyl chains on the surface of ODA-functionalized GO nanosheets (ODA-GO) are in favor of C3H8 adsorption, thus conferring continuous and specific transport pathways for C3H8. The optimized membrane with ODA-GO loading of 0.3 wt% exhibits the C3H8 permeance of 1897 GPU and the C3H8/N-2 ideal selectivity of 67, which are 50.2 and 72.5% higher than those of bare PDMS membrane, respectively. The simultaneous enhancement of C3H8 permeance and C3H8/N-2 ideal selectivity indicates that ODA-GO is an effective filler applied in MMMs for C3H8 recovery. (C) 2017 American Institute of Chemical Engineers AIChE