화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.55, 119-127, November, 2017
DOI10.1016/j.jiec.2017.06.035  Export Citation
CrOx-MnOx-TiO2 adsorbent with high resistance to SO2 poisoning for Hg0 removal at low temperature
Guanyi Chen1, †, Dan Zhang1, 2, Anchao Zhang3, †, Zhihui Zhang3, Zhichao Liu3, and Li’an Hou4
  • 1School of Environmental Science and Engineering, Tianjin University, Tianjin 300072, China
  • 2School of Civil Engineering, Henan Polytechnic University, Jiaozuo 454003, China
  • 3School of Mechanical and Power Engineering, Henan Polytechnic University, Jiaozuo 454003, China
  • 4Rocket Force University of Engineering, Xi’an 710025, China
E-mail:,
Chromium modified MnOx-TiO2 (CMT), MnOx-TiO2 (MT) and CrOx-TiO2 (CT) adsorbents were prepared by a sol.gel method and were investigated for Hg0 removal in the absence and presence of SO2. The fresh and used adsorbents were characterized by N2 physisorption, XRD, FTIR, H2-TPR, XPS and TG. The results showed that the addition of Cr into MT can not only increase the activity of Hg0 removal, but also improve its SO2 resistance performance. The amount of manganese sulfate formed onto spent CMT was much higher than that of chromium sulfate, meaning that sulfate species were formed preferentially on Mn rather than Cr.
Keywords:Hg0 removal;CrOx;MnOx;Adsorbent;SO2 resistance
  1. Xu WQ, Wang HR, Zhou X, Zhu TY, Chem. Eng. J., 243, 380 (2014)
  2. Cho JH, Eom Y, Jeon SH, Lee TG, J. Ind. Eng. Chem., 19(1), 144 (2013)
  3. Dabrowski JM, Ashton PJ, Murray K, Leaner JJ, Mason RP, Atmos. Environ., 42, 6620 (2008)
  4. Pirrone N, Cinnirella S, Feng XB, Finkelman RB, Friedli HR, Leaner J, Mason R, Mukherjee AB, Stracher GB, Streets DG, Telmer K, Atmos. Chem. Phys., 10, 5951 (2010)
  5. Cao Y, Gao Z, Zhu J, Wang Q, Huang Y, Chiu C, Parker B, Chu P, Pan WP, Environ. Sci. Technol., 42, 256 (2008)
  6. Granite EJ, Myers CR, King WP, Stanko DC, Pennline HW, Ind. Eng. Chem. Res., 45(13), 4844 (2006)
  7. Sjostrom S, Durham M, Bustard CJ, Martin C, Fuel, 89(6), 1320 (2010)
  8. Vidic RD, Siler DP, Carbon, 39, 3 (2001)
  9. Yang SJ, Guo YF, Yan NQ, Wu DQ, He HP, Qu Z, Jia JP, Ind. Eng. Chem. Res., 50(16), 9650 (2011)
  10. Wu J, Li X, Ren J, Qi X, He P, Ni B, Zhang C, Hu C, Zhou J, J. Ind. Eng. Chem., 32, 49 (2015)
  11. Reddy KSK, Shoaibi AA, Srinivasakannan C, J. Ind. Eng. Chem., 20(5), 2969 (2014)
  12. Presto AA, Granite EJ, Environ. Sci. Technol., 40, 5601 (2006)
  13. Granite EJ, Pennline HW, Hargis RA, Ind. Eng. Chem. Res., 39(4), 1020 (2000)
  14. Wei ZS, Luo YW, Li BR, Chen ZY, Ye QH, Huang QR, He JC, J. Ind. Eng. Chem., 24, 315 (2015)
  15. Wang P, Su S, Xiang J, You H, Cao F, Sun L, Hu S, Zhang Y, Chemosphere, 101, 49 (2014)
  16. He C, Shen B, Chen J, Cai J, Environ. Sci. Technol., 48, 7891 (2014)
  17. Li J, Chen J, Yu Y, He C, J. Ind. Eng. Chem., 25, 352 (2015)
  18. Wang PY, Su S, Xiang J, Cao F, Sun LS, Hu S, Lei SY, Chem. Eng. J., 225, 68 (2013)
  19. Xu HM, Xie JK, Ma YP, Qu Z, Zhao SJ, Chen WM, Huang WJ, Yan NQ, Fuel, 140, 803 (2015)
  20. Reddy GK, He J, Thiel SW, Pinto NG, Smirniotis PG, J. Phys. Chem., 56, 110 (2015)
  21. Zhang AC, Zhang ZH, Lu H, Liu ZC, Xiang J, Zhou CS, Xing WB, Sun LS, Ind. Eng. Chem. Res., 54(11), 2930 (2015)
  22. Li HL, Wu CY, Li Y, Li LQ, Zhao YC, Zhang JY, J. Hazard. Mater., 243, 117 (2012)
  23. Jampaiah D, Ippolito SJ, Sabri YM, Reddy BM, Bhargava SK, Catal. Sci. Technol., 5, 2913 (2015)
  24. Jampaiah D, Ippolito SJ, Sabri YM, Tardio J, Selvakannan PR, Nafady A, Reddy BM, Bhargava SK, Catal. Sci. Technol., 6, 1792 (2015)
  25. Zhou CC, Zhang YP, Wang XL, Xu HT, Sun KQ, Shen K, J. Colloid Interface Sci., 392, 319 (2013)
  26. Chen JH, Zhang XY, Arandiyan H, Peng Y, Chang HZ, Li JH, Catal. Today, 201, 12 (2013)
  27. Zhao HH, Song HL, Xu LL, Chou LJ, Appl. Catal. A: Gen., 456, 188 (2013)
  28. Chen ZH, Yang Q, Li H, Li XH, Wang LF, Tsang SC, J. Catal., 276(1), 56 (2010)
  29. Yang R, Huang H, Chen Y, Zhang X, Lu H, Chin. J. Catal., 36, 1256 (2015)
  30. Ordonez S, Paredes JR, Diez FV, Appl. Catal. A: Gen., 341(1-2), 174 (2008)
  31. Qian Y, Ma C, Niu D, Xu J, Li M, Corrosion Sci., 74, 424 (2013)
  32. Zhang AC, Zheng WW, Song J, Hu S, Liu ZC, Xiang J, Chem. Eng. J., 236, 29 (2014)
  33. Qiao SH, Chen J, Li JF, Qu Z, Liu P, Yan NQ, Jia JQ, Ind. Eng. Chem. Res., 48(7), 3317 (2009)
  34. Zhang LJ, Cui SP, Guo HX, Ma XY, Luo XG, Appl. Surf. Sci., 355, 1116 (2015)
  35. Yang P, Shi ZN, Yang SS, Zhou RX, Chem. Eng. Sci., 126, 361 (2015)
  36. Sheng Z, Hu Y, Xue J, Wang X, Liao W, J. Rare Earths, 30, 676 (2012)
  37. Jensen H, Soloviev A, Li ZS, Sogaard EG, Appl. Surf. Sci., 246(1-3), 239 (2005)
  38. Zhang MY, Li CT, Qu L, Fu MF, Zeng GM, Fan CZ, Ma JF, Zhan FM, Appl. Surf. Sci., 300, 58 (2014)
  39. Deshmukh SS, Zhang MH, Kovalchuk VI, d'Itri JL, Appl. Catal. B: Environ., 45(2), 135 (2003)
  40. Tang N, Liu Y, Wang H, Wu Z, J. Phys. Chem., 115, 8214 (2011)
  41. Wu XD, Liu SA, Weng DA, Lin F, Ran R, J. Hazard. Mater., 187(1-3), 283 (2011)
  42. Delimaris D, Ioannides T, Appl. Catal. B: Environ., 84(1-2), 303 (2008)
  43. Kijlstra WS, Biervliet M, Poels EK, Bliek A, Appl. Catal. B: Environ., 16(4), 327 (1998)
  44. Liu FD, Asakura K, He H, Shan WP, Shi XY, Zhang CB, Appl. Catal. B: Environ., 103(3-4), 369 (2011)
  45. Wu Z, Jin R, Wang H, Liu Y, Catal. Commun., 10, 935 (2009)
  46. Karami A, Salehi V, J. Catal., 292, 32 (2012)
  47. Yim SD, Koh DJ, Nam IS, Catal. Today, 75(1-4), 269 (2002)
  48. Du XS, Gao X, Cui LW, Fu YC, Luo ZY, Cen KF, Fuel, 92(1), 49 (2012)
  49. Zhao Y, Hao RL, Zhang P, Zhou SH, Fuel, 136, 113 (2014)
  50. Xu JJ, Ao YH, Fu DG, Yuan CW, Appl. Surf. Sci., 254(10), 3033 (2008)
  51. Li J, Chen J, Ke R, Luo C, Hao J, Catal. Commun., 8, 1896 (2007)
  52. Xu YL, Zhong Q, Liu XY, J. Hazard. Mater., 283, 252 (2015)
  53. Kim YJ, Kwon HJ, Heo I, Nam IS, Cho BK, Choung JW, Cha MS, Yeo GK, Appl. Catal. B: Environ., 126, 9 (2012)
  54. Guo Y, Yan N, Yang S, Liu P, Wang J, Qu Z, Jia J, J. Hazard. Mater., 213-214, 62 (2012)