화학공학소재연구정보센터
Journal of Physical Chemistry A, Vol.101, No.27, 4954-4965, 1997
Synchronization of Oscillations and Propagation of Excitations in Circular and Linear Arrays of Coupled CSTRs
Synchronizations of oscillatory regimes of the Belousov-Zhabotinskii (BZ) reaction in a circular array of three identical CSTRs coupled via symmetric passive diffusion/convection mass transfer were studied experimentally. Stability of symmetric and asymmetric phase-shifted oscillatory regimes with respect to variations of the coupling strength among the reaction cells was examined. The all-in-phase regime was found to be the only regime stable over the entire range of coupling strength values. Phase-shifted oscillatory regimes were found to be stable only within a narrow interval of very low coupling strength values. Spontaneous transitions of the phase-shifted regimes to the synchronized mode due to stochastic fluctuations of the coupling strength were observed. Numerical simulations with the four-variable Oregonator based model of the BZ reaction qualitatively confirmed the experimental findings. Propagation of an excitable response to periodic pulsed stimulations in a linear three-array of coupled chemical excitators (Belousov-Zhabotinskii reaction) was studied in dependence on the coupling strength, on the excitability level of the reaction mixture, and on the period and amplitude of pulse stimulation. Regimes of complete and partial propagation of the excitable response and the regimes of partial and complete propagation failure were observed. Numerical simulations predict qualitatively well excitatory regimes observed in experiments.