화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.54, 324-331, October, 2017
DOI10.1016/j.jiec.2017.06.007  Export Citation
Studies on the correlation between nanostructure and pore development of polymeric precursor-based activated hard carbons: II. Transmission electron microscopy and Raman spectroscopy studies
Jin Baek1, 2, Hyung-Shik Shin2, Dong Chul Chung1, and Byung-Joo Kim1, †
  • 1R&D Division, Korea Institute of Carbon Convergence Technology, Jeonju 54853, Republic of Korea
  • 2Department of Chemical Engineering, Chonbuk National University, Jeonju 54896, Republic of Korea
E-mail:
In a previous study, we reported on activated polymer-based hard carbons (APHCs), which were prepared using CO2 activation and characterized according to activation conditions, including textural properties such as specific surface area and pore volume. This paper was focused on the correlation between nanostructure and pore development of APHCs by using Cs-corrected-field emission transmission electron microscopy (Cs-corrected FE-TEM) and Raman spectroscopy to supplement the in-depth explanation. In the TEM analysis, the APHCs were observed to contain slit-shaped pores (SPs) and little cylindrical pores (CPs). And Raman spectroscopy was used in order to determine the degree of development of the crystal size (La) in the APHCs. The size of La increased with increasing activation time until it was nearly 3 nm. These small crystallites might cause the SPs development, resulting in the high micropore volume of the APHCs. From a result of Raman analysis, it was confirmed that the La value and the ratio of ID/IG value were in a proportional relation. The reason for this relation is that the La value has grown up to about 3 nm, which is consistent with the Ferrari equation.
Keywords:Nanotexture;Hard carbon;TEM;Raman spectroscopy;Slit pore
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