화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.53, 325-332, September, 2017
DOI10.1016/j.jiec.2017.05.003  Export Citation
Surface modification of graphene oxide by pyridine derivatives for copper(II) adsorption from aqueous solutions
Yuexin Guo1, 2, Zhiqian Jia1, 3, †, and Meijuan Cao4
  • 1College of Chemistry, Beijing Normal University, Beijing, 100875, PR China
  • 2School of Pharmacy, North China University of Science and Technology, Tangshan, 063009, PR China
  • 3State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian, 116024, PR China
  • 4Beijing Engineering Research Center of Printed Electronics, Beijing Institute of Graphic Communication, Beijing, 102600, PR China
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Graphene oxide (GO) was covalently modified by series of pyridine derivatives with SOCl2 activation method for adsorption of Cu(II) for the first time. The effects of pyridine derivatives structure, adsorption thermodynamics, kinetics and adsorbents reusability were investigated. The adsorption capacity of modified GO is related to the number of pyridine groups, and substituent position. The maximum adsorption capacity of 4'-carboxy-2,2':60,2"-terpyridine modified GO (GO-CTPy) reaches 119.6 mg g-1, which is much higher than that of other modified GO. The adsorption can be well described by the Langmuir isotherm model and pseudo-second-order kinetic model. GO-CTPy exhibited excellent regeneration and reusability.
Keywords:Graphene oxide;Adsorption;Pyridine derivatives;Surface modification;Copper(II)
  1. Morin S, Duong TT, Dabrin A, Coynel A, Herlory O, Baudrimont M, et al.,, Environ. Pollut., 151(3), 532 (2008)
  2. Liu WH, Zhao JZ, Ouyang ZY, Soderlund L, Liu GH, Environ. Int., 31(6), 805 (2005)
  3. US EPA, Pesticide Tolerances; Exemptions from Requirements: Copper Sulfate Pentahydrate, Federal Register, 2013-3110, 78727.78731.
  4. Gu HB, Chen WY, Zhao CQ, J. Am. Leather Chem. Assoc., 103(3), 114 (2008)
  5. Agency for Toxic Substances Disease Registry (ATSDR), Toxicological Profiles for Copper, U.S. Department of Health and Human Services, Public Health Service, Atlanta, 2004 137.
  6. Crawford DW, Bonnevie NL, Wenning RJ, Ecotox. Environ. Safe., 30(1), 85 (1995)
  7. Pan K, Zhu AJ, Xu ZB, Wang WX, Assoc. J. Ecotoxicol., 9(4), 618 (2014)
  8. Wang WX, Yang YB, Guo XY, He M, Guo F, Ke CH, et al., Environ. Toxicol. Chem., 30(8), 167 (2011)
  9. Olivares M, Araya M, Pizarro F, Uauy R, et al., Regul. Toxicol. Pharmacol., 33(3), 271 (2001)
  10. Araya M, McGoldrick MC, Klevay LM, Strain JJ, Robson P, Nielsen F, et al., Regul. Toxicol. Pharmacol., 34(2), 137 (2001)
  11. Ahasan HAMN, Chowdhury MAJ, Azhar MA, Rafiqueuddin AKM, Trop. Doct., 24(2), 52 (1994)
  12. Chuttani HK, Gupta PS, Gulati S, Gupta DN, Am. J. Med., 39(5), 849 (1965)
  13. Ministry of Environmental Protection of PRC, General Administration of Quality Supervision, Inspection and Quarantine of PRC, Environmental quality standards for surface water, GB 3838-2002.
  14. Ministry of Environmental Protection of PRC, General Administration of Quality Supervision, Inspection and Quarantine of PRC, Emission standards of pollutants for inorganic chemical industry, GB 31573-2015.
  15. Mirbagheri SA, Hosseini SN, Desalination, 171(1), 85 (2005)
  16. Bessbousse H, Rhlalou T, Verchere JF, Lebrun L, J. Membr. Sci., 307(2), 249 (2008)
  17. Dabrowski A, Hubicki Z, Podkoscielny P, Robens E, Chemosphere, 56(2), 91 (2004)
  18. Bilal M, Shah JA, Ashfaq T, Gardazi SMH, Tahir AA, Pervez A, Haroon H, Mahmood Q, J. Hazard. Mater., 263, 322 (2013)
  19. Tripathi A, Burkhard C, Suni II, Li YZ, Doniat F, Barajas A, et al., J. Electrochem. Soc., 155, 918 (2008)
  20. Fu FL, Wang Q, J. Environ. Manage., 92(3), 407 (2011)
  21. Peric J, Trgo M, Medvidovic NV, Water Res., 38(7), 1893 (2004)
  22. Monser L, Adhoum N, Sep. Purif. Technol., 26(2-3), 137 (2002)
  23. Tofighy MA, Mohammadi T, J. Hazard. Mater., 185(1), 140 (2011)
  24. Demirbas A, Pehlivan E, Gode F, Altun T, Arslan G, J. Colloid Interface Sci., 282(1), 20 (2005)
  25. Stoller MD, Park SJ, Zhu YW, An JH, Ruoff RS, Nano Lett., 8(10), 3498 (2008)
  26. Dikin DA, Stankovich S, Zimney EJ, Piner RD, Dommett GHB, Evmenenko G, et al., Nature, 448(7152), 457 (2007)
  27. Wang SB, Sun HQ, Ang HM, Tade MO, Chem. Eng. J., 226, 336 (2013)
  28. Lv HL, Guo YH, Zhao Y, Zhang HQ, Zhang BS, Ji GB, et al., Carbon, 110, 130 (2016)
  29. Dikin DA, Stankovich S, Zimney EJ, Piner RD, Dommett GHB, Evmenenko G, et al., Nature, 448(7152), 457 (2007)
  30. Li XY, Zhou HH, Wu WQ, Wei SD, Xu Y, Kuang YF, J. Colloid Interface Sci., 448, 389 (2015)
  31. Hu XJ, Liu YG, Wang H, Zeng GM, Hu X, Guo YM, Li TT, Chen AW, Jiang LH, Guo FY, Chem. Eng. Res. Des., 93, 675 (2015)
  32. Zhang KX, Li HY, Xu XJ, Yu HW, Ind. Eng. Chem. Res., 55(8), 2328 (2016)
  33. Roesky HW, Andruh M, Coord. Chem. Rev., 236(1-2), 91 (2003)
  34. Hummers WS, Offeman RE, J. Am. Chem. Soc., 80(6), 1339 (1958)
  35. Marcano DC, Kosynkin DV, Berlin JM, Sinitskii A, Sun ZZ, Slesarev A, et al., ACS Nano, 4(8), 4806 (2010)
  36. Jia ZQ, Shi WX, Carbon, 101, 290 (2016)
  37. Kumar NA, Choi HY, Shin TR, Chang DE, Dai LM, Baek JB, ACS Nano, 6, 1715 (2012)
  38. Park JS, Cho SM, Kim WJ, Park J, Yoo PJ, ACS Appl. Mater. Interfaces, 3(3), 360 (2011)
  39. Hoseini SJ, Khozestan HG, Fath RH, RSC Adv., 5(59), 4771 (2015)
  40. Ministry of Environmental Protection of PRC, Water quality-determination of copper-2,9-dimethy-1,10-phenanthroline spectrophotometric method, State environmental protection standards of PRC, HJ 486-2009.
  41. Hassanpour A, Miguel DRS, Fierro JLG, Horrocks BR, Mas- Ballest, R Zamora F, Chem. Eur. J., 19(32), 10463 (2013)
  42. Zhang F, Jiang HY, Li XY, Wu XT, Li HX, ACS Catal., 4(2), 394 (2014)
  43. Becerril HA, Mao J, Liu Z, Stoltenberg RM, Bao Z, Chen Y, ACS Nano, 2, 463 (2008)
  44. Lomeda JR, Doyle CD, Kosynkin DV, Hwang WF, Tour JM, J. Am. Chem. Soc., 130(48), 16201 (2008)
  45. Jia ZQ, Shi WX, Wang Y, Wang JL, Colloids Surf. A: Physicochem. Eng. Asp., 494, 101 (2016)
  46. Hoseini SJ, Heidari V, Nasrabadi H, J. Mol. Catal. A-Chem., 396, 90 (2015)
  47. Perreault F, Tousley ME, Elimelech M, Environ. Sci. Technol., 1(1), 71 (2014)
  48. Jia ZQ, Wang Y, J. Mater. Chem., 3(8), 4405 (2015)
  49. Sui ZY, Cui Y, Zhu JH, Han BH, ACS Appl. Mater. Interfaces, 5(18), 9172 (2013)
  50. Dreyer DR, Park S, Bielawski CW, Ruoff RS, Chem. Soc. Rev., 39(1), 228 (2010)
  51. Li N, Bai RB, Sep. Purif. Technol., 42(3), 237 (2005)
  52. Villaescusa I, Fiol N, Martinez M, Miralles N, Poch J, Serarols J, Water Res., 38(4), 992 (2004)
  53. Ngah WSW, Endud CS, Mayanar R, React. Funct. Polym., 50(2), 181 (2002)
  54. Feng NC, Guo XY, Liang S, J. Hazard. Mater., 164(2-3), 1286 (2009)
  55. Alvarez-Torrellas S, Ribeiro RS, Gomes HT, Ovejero G, Garcia J, Chem. Eng. J., 296, 277 (2016)
  56. Lagergren S, Sven K, Vetenskapsakad. Handl., 24(4), 1 (1898)
  57. Ho YS, Scientometrics, 59(1), 171 (2004)
  58. Agarwal S, Sadegh H, Monajjemi M, Hamdy AS, Ali GAM, Memar AOH, Shahryari-ghoshekandi R, Tyagi I, Gupta VK, J. Mol. Liq., 218, 191 (2016)
  59. Shahryari-ghoshekandi R, Sadegh H, Jordan J. Chem., 9(4), 267 (2014)
  60. Ho YS, McKay G, Chem. Eng. J., 70(2), 115 (1998)
  61. Gupta VK, Agarwal S, Bharti AK, Sadegh H, J. Mol. Liq., 230, 667 (2017)
  62. Vu TA, Le GH, Dao CD, Dang LQ, Nguyen KT, Nguyen QK, et al., RSC Adv., 5(7), 5261 (2015)
  63. Mclintoc IS, Nature, 216(5121), 1204 (1967)
  64. Chien SH, Clayton WR, Soil Sci. Soc. Am. J., 44(2), 265 (1980)
  65. Weber WJ, Morris JC, Sanit J, Eng. Div. Am. Soc. Civ. Eng., 89(5), 31 (1963)
  66. Sadegh H, Ali GAM, Gupta VK, Makhlouf ASH, Shahryari-Ghoshekandi R, Nadagouda MN, Sillanpaa M, Megie E, J. Nanostruct. Chem., 7(1), 11 (2017)