화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.53, 134-142, September, 2017
DOI10.1016/j.jiec.2017.04.014  Export Citation
A potential industrialized fiber-supported copper catalyst for one-pot multicomponent CuAAC reactions in water
Xian-Lei Shi1, 2, †, Yongju Chen3, Qianqian Hu3, Wenqin Zhang2, Chenxu Luo3, and Peigao Duana3, †
  • 1Henan Polytechnic University, Jiaozuo, Henan 454003, PR China
  • 2Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Tianjin University, Tianjin 300072, PR China
  • 3Henan Polytechnic University,, Jiaozuo, Henan 454003, PR China
E-mail:,
A potential industrialized fiber catalyst for “click chemistry” via the one-pot multicomponent Cu(I)-catalyzed azide-alkyne cycloaddition (CuAAC) for the synthesis of 1,2,3-triazoles in water, is reported. Detailed characterization by appearance, mechanical properties, elemental analysis, FTIR spectroscopy, and SEM confirmed the rangeability of the fiber catalyst during the preparation and utilization processes. Moreover, the fiber catalyst-mediated reactions proceeded smoothly to afford triazoles with nearly quantitative yields in short time (15 min). Furthermore, the fiber catalyst has shown tandem activities and superior recyclability (over 10 cycles), and the procedure is operationally simple and amenable to the gram-scale on a simple fixed-bed reactor.
Keywords:Fiber catalyst;Tandem catalysis;Click chemistry;CuAAC reaction;Fixed-bed reactor
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