화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.53, 119-126, September, 2017
DOI10.1016/j.jiec.2017.04.012  Export Citation
Metathesis of 2-pentene over Mo and W supported mesoporous molecular sieves MCM-41 and SBA-15
Mohamed Ali Ibrahim1, Muhammad Naseem Akhtar1, Jiri Cejka1, 2, Erica Montanari3, Hynek Balcar2, Martin Kubu2, and Sulaiman S. Al-Khattaf1, †
  • 1Center of Research Excellence in Petroleum Refining and Petrochemicals, King Fahd University of Petroleum & Minerals, Dhahran 31261, Saudi Arabia
  • 2J. Heyrovsky Institute of Physical Chemistry, Academy of Sciences of Czech Republic
  • 3Eni s.p.a., Research & Technological Innovation, Physical Chemistry Dept., Via F. Maritano 26,I-20097 San Donato Milanese, Italy
E-mail:
Molybdenum and tungsten oxides were supported on silica, MCM-22, MCM-41 and SBA-15. XRD and N2 adsorption.desorption revealed that architecture and textural character of supports were preserved. The catalysts were investigated in transformation of 2-pentene at different reaction temperatures. MoO3/ MCM-22 exhibited highest conversions with isomerization and cracking as major reactions. MoO2(acac)2, MoO3 and WO3 supported on MCM-41 and SBA-15 showed metathesis reaction of 2-C5 = producing propylene, C4 = and C6+=as major products. Catalysts based on MCM-41 exhibited higher activity and stability than SBA-15. Addition of ethylene to 2-C5 = increased selectivity to propylene due to metathesis of ethylene with 2-pentene.
Keywords:Metathesis;MCM-41;SBA-15;2-Pentene;Molybdenum oxide
  1. Aitani AM, Encycl. Chem. Process 2014 (May) (2006) 2461.
  2. Ivin KJ, Mol JC, Olefin Metathesis Metathesis Polymerization, Academic Press, London, 1997 Chapter 17.
  3. Mol JC, van Leeuwen PWNM, 2nd edition, Handbook of Heterogeneous Catalysis, vol. 14, Wiley, Weinheim, 2008, pp. 3240.
  4. Hua DR, Chen SL, Yuan GM, Wang YL, Zhao QF, Wang XL, Fu B, Microporous Mesoporous Mater., 143, 320 (2011)
  5. Mol JC, Leeuwen PWM, Metathesis of alkenes, Handbook of Heterogeneous Catalyst, vol. 8(2008) , pp. 3240.
  6. Huang SJ, Liu SL, Xin WJ, Bai J, Xie SJ, Wang QX, Xu LY, J. Mol. Catal. A-Chem., 226(1), 61 (2005)
  7. Balcar H, Hamtil R, Zilkova N, Cejka J, Catal. Lett., 97(1-2), 25 (2004)
  8. Maksimowski P, Skupinski W, J. Mol. Catal., 65, 187 (1991)
  9. Topka P, Balcar H, Rathousky J, Zilkova N, Verpoort F, Cejka J, Microporous Mesoporous Mater., 96, 44 (2006)
  10. Sang L, Chen SL, Yuan GM, Zheng M, You J, Chen AE, Li R, Chen LJ, J. Nat. Gas Chem., 21, 105 (2012)
  11. Phongsawat W, Netivorruksa B, Suriye K, Dokjampa S, Praserthdam P, Panpranot J, J. Nat. Gas Chem., 21, 83 (2012)
  12. Phongsawat W, Netiworaruksa B, Suriye K, Praserthdam P, Panpranot J, Catal. Lett., 142(9), 1141 (2012)
  13. Behr A, Schuller U, Bauer K, Maschmeyer D, Wiese KD, Nierlich F, Appl. Catal. A: Gen., 357(1), 34 (2009)
  14. Spamer A, Dube TI, Moodley DJ, van Schalkwyk C, Botha JM, Appl. Catal. A: Gen., 255(2), 133 (2003)
  15. Balcar H, Mishra D, Marceau E, Carrier X, Zilkova N, Bastl Z, Appl. Catal. A: Gen., 359(1-2), 129 (2009)
  16. Huang SJ, Chen FC, Liu SL, Zhu QJ, Zhu XX, Xin WJ, Feng ZC, Li C, Wang QX, Xu LY, J. Mol. Catal. A-Chem., 267(1-2), 224 (2007)
  17. Zhao Q, Chen SL, Gao J, Xu C, Transit. Met. Chem., 34, 621 (2009)
  18. Hua D, Chen SL, Yuan G, Wang Y, Zhang L, Transit. Met. Chem., 36, 245 (2011)
  19. Lwin S, Wachs IE, ACS Catal., 4, 2505 (2014)
  20. Gholampour N, Yusubov M, Verpoort F, Catal. Rev.-Sci. Eng., 58(1), 113 (2016)
  21. Wang YD, Chen QL, Yang WM, Xie ZK, Xu X, Huang D, Appl. Catal. A: Gen., 250(1), 25 (2003)
  22. Chaemchuen S, Phatanasri S, Verpoort F, Sae-ma N, Suriye K, Kinet. Catal., 53, 247 (2012)
  23. Harmse L, van Schalkwyk C, van Steen E, Catal. Lett., 137(3-4), 123 (2010)
  24. Liu H, Zhang L, Li X, Huang S, Liu S, Xin W, Xie S, Xu LY, J. Nat. Gas Chem., 18, 331 (2009)
  25. Huang S, Liu S, Xin W, Xie S, Wang Q, Xu L, J. Nat. Gas Chem, 15, 93 (2006)
  26. Huang SJ, Liu SL, Xin WJ, Bai J, Xie SJ, Wang QX, Xu LY, J. Mol. Catal. A-Chem., 226(1), 61 (2005)
  27. Kresge CT, Leonowicz ME, Roth WJ, Vartuli JC, Stud. Surf. Sci. Catal., 148, 53 (2004)
  28. Beck JS, Vartuli JC, Roth WJ, Leonowicz ME, Kresge CT, Schmitt KD, Chu CTW, Olson DH, Sheppard EW, McCullen SB, Higgins JB, Schlenker JL, J. Am. Chem. Soc., 114, 10834 (1992)
  29. Martin-Arranda RM, Cejka J, Top. Catal., 53, 141 (2010)
  30. Kresge CT, Roth WJ, Chem. Soc. Rev., 42, 3663 (2013)
  31. Xie WL, Zhao LL, Energy Conv. Manag., 79, 34 (2014)
  32. Xie WL, Fan ML, Chem. Eng. J., 239, 60 (2014)
  33. Xie W, Zang X, Food Chem., 194, 1283 (2016)
  34. Xie WL, Yang XL, Fan ML, Renew. Energy, 80, 230 (2015)
  35. Balcar H, Cejka J, Coord. Chem. Rev., 257, 3107 (2013)
  36. Balcar H, Cejka J, Macromol. Symp., 293, 43 (2010)
  37. Ookoshi T, Onaka M, Chem. Commun., 2399, 1998
  38. Bhuiyan TI, Arudra P, Akhtar MN, Aitani AM, Abudawoud RH, Al-Yami MA, Al-Khattaf SS, Appl. Catal. A: Gen., 467, 224 (2013)
  39. Hahn T, Kondratenko EV, Linke D, Chem. Commun., 50, 9060 (2014)
  40. Hahn T, Bentrup U, Armbruster M, Kondratenko EV, Linke D, ChemCatChem, 6, 1664 (2014)
  41. Amakawa K, Krohnert J, Wrabetz S, Frank B, Hemmann F, Jager C, Schlogl R, Trunschke A, ChemCatChem, 7, 4059 (2015)
  42. Marquez-Alvarez C, Zilkova N, Perez-Pariente J, Cejka J, Catal. Rev.-Sci. Eng., 50(2), 222 (2008)
  43. Kresge CT, Roth WJ, Simmons KG, Vartuli JC, U.S. Patent 5,266,541 (1993).
  44. Collart O, Van Der Voort P, Vansant EF, Gustin E, Bouwen A, Schoemaker D, Rao RR, Weckhuysen BW, Schoonheydt RA, Phys. Chem. Chem. Phys., 1, 4099 (1999)
  45. Maksasithorn S, Debecker DP, Praserthdam P, Panpranot J, Suriye K, Na Ayudhya SK, Chin. J. Catal., 35, 232 (2014)
  46. Ivin KJ, Mol JC, Olefin Metathesis Metathesis Polymerization, Academic Press, London, 1997 Chapter 2.