Thin Solid Films, Vol.628, 203-207, 2017
Preparation of titanium dioxide thin films by indirect-electrodeposition
Titanium oxide films were prepared on a quartz glass substrate by the cathodic galvanostatic electrolysis of a solution of titanium bis(ammonium lactato)dihydroxide and ammonium nitrate at 323 K using a stainless steel electrode as a "dummy electrode" located in the vicinity (within similar to 1 mm) of the substrate. This novel film preparation method, named "indirect-electrodeposition" is effective for nonconductive substrates without catalysts or reducing agents. During indirect electrodeposition, the films are deposited on the area of the substrate above the electrolyte solution surface. The deposited film was identified as TiO2 by X-ray photoelectron spectroscopy. The amorphous as-deposited film was converted to the anatase-type crystalline TiO2 phase by calcination at 723 K. Optical bandgap of the film was evaluated with Kubelka-Munk function from diffuse reflection spectra. (C) 2017 Elsevier B.V. All rights reserved.
Keywords:Titanium oxide films;Titanium bis(ammonium lactato)dihydroxide;Electrodeposition;Capillary action;Direct transition