화학공학소재연구정보센터
International Journal of Hydrogen Energy, Vol.42, No.21, 14794-14808, 2017
Comparison of the explosion characteristics of hydrogen, propane, and methane clouds at the stoichiometric concentrations
Numerical simulations were performed to study explosion characteristics of the unconfined clouds. The examined cloud volume was 4m x 4m x 2 m. The build -in obstruction inside the cloud was the 8 x 8 x 4 perpendicular rod array. The obstacle volume blockage ratio was 0.74. Three gases were considered: hydrogen/air at the stoichiometric concentrations, propane/air at the stoichiometric concentrations, and methane/air at the stoichiometric concentrations. The hydrogen/air cloud explosion has higher peak overpressure and the overpressure rises locally at the nearby region of the cloud boundary. The explosion overpressures of both methane/air and propane/air are lower, compared with the hydrogen/air, and decreases With distance. The maximum peak dynamic pressure is reached beyond the original cloud, which is clearly different from the explosion peak overpressure tends. Furthermore, dynamic pressure of a cloud explosion is of the same order as overpressure. The explosion flame region for the hydrogen/air cloud is approximately 1.25 times of the original width of the cloud. The explosion flame regions for propane/air or methane/air clouds are approximately 1.4 times of the original width of the cloud. Unlike the explosion overpressures, the explosion temperatures have little difference between the three mixture examined in this study. The higher energy of explosive mixture generates a high temperature hazard effect, but the higher energy of explosive mixture may not generate a larger overpressure hazard effect in a gas explosion accident. (C) 2017 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.