International Journal of Hydrogen Energy, Vol.42, No.21, 14583-14592, 2017
Porous stainless steel support for hydrogen separation Pd membrane; fabrication by metal injection molding and simple surface modification
We prepared a disc-shaped porous stainless steel (PSS) support for hydrogen separation Pd membrane via metal injection molding (MIM) method to facilitate the mass production of porous substrates. MIMed PSS supports obtained in a batch showed relatively higher apparent porosity (from 32.75% to 39.28%) than that reported for commercially available PSS substrate. In addition, the surface morphologies of the MIMed PSS, surface roughness of 1.119 mu m and pore depth of 8.6 mu m, indicate its suitability as a membrane support than the commercially available one. Pd membrane prepared over MIMed PSS, which was modified by a simple axial pressing method to control the surface morphologies, had a thinner Pd layer, 2.94 mu m, and showed an extremely higher ideal H-2/N-2 selectivity with a hydrogen permeation flux of 21.3 mVmin/cm(2) at del-P = 1 bar and 400 degrees C, compared with Pd membrane over MIMed PSS modified with conventional surface modification. (C) 2017 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
Keywords:Porous stainless steel support;Pd membrane;Hydrogen;Metal injection molding;Surface modification