화학공학소재연구정보센터
Energy, Vol.131, 230-238, 2017
Efficiency enhancement of a-Si and CZTS solar cells using different thermoelectric hybridization strategies
The performances of two hybrid thermoelectric photovoltaic systems are compared. In the first instance, a photovoltaic (PV) device and a thermoelectric generator (TEG) are optically coupled using a vacuum -sealed compound parabolic concentrator (CPC). As an alternative, PV and TEG devices are thermally coupled putting them directly in contact to each other. Single-junction a-Si and heterojunction Cu2ZnSnS4 (CZTS) have been considered as PV systems. The two systems are studied by varying the heat transfer coefficient of the cooling system between the TEG cold side and the ambient, the TEG device fill factor, and the optical concentration. Hybridization, in both configurations, always enhances the efficiencies, up to approximate to 57% for single junction a-Si and up to approximate to 35% for the heterojunction CZTS. It will be shown that while direct thermal contact enables larger efficiencies, optical coupling grants lower temperatures at the PV side, enhancing reliability and lifetime. Further advantages and limitations of both configurations will be discussed. (C) 2017 Elsevier Ltd. All rights reserved.