Pyrolytic poly-generation of three algae (Enteromorpha prolifera (EP), Spirulina platensis (SP) and Nannochloropsis sp. (NS)) was carried out in a fixed bed reactor and pyrolysis mechanism was explored in detail. Influences of pyrolysis temperature (400-800 degrees C) and biochemical components (carbohydrates, proteins and lipids) of algae on pyrolytic behavior and products characteristics were investigated. EP showed higher char yield, while SP and NS showed high bio-oil yields. At lower temperature (400-500 degrees C), CO2 was the main gas product, while H-2, CH4 and CO evolved out quickly with temperature increasing. EP cracking could release more CO, while SP and NS cracking could release more H-2, CH4 and C-2. While for bio-oil, it was variant with algae composition and temperature, as EP showed higher furans, SP yielded large amounts of N-containing chemicals, while aliphatics and carboxylic acids were the dominated components for NS. However, aromatics gradually became the major compounds for all bio-oil at 700-800 degrees C. For char, C-O/C-O-C/C=N, C=O/C-N and COO- groups cracking gradually with temperature increasing and resulted in more aromatic C=C. The optimum operating temperature is 500-600 degrees C for algae pyrolytic poly-generation to achieve higher value of char, bio-oil and gas products together. (C) 2017 Elsevier Ltd. All rights reserved.