The solubility and supersolubility of 3,4-bis(3-nitrofurazan-4-yl) furoxan (DNTF) in ethanol+ water at different operation were determined by laser monitoring system under atmospheric pressure to study the metastable zone width (MSZW). The modified Apelblat equation was adopted to correlate the experimental solubility data, and the correlation result showed perfect consistent with the experimental data. The standard dissolution enthalpy, standard dissolution entropy and Gibbs energy were calculated according to the experimental solubility data. The effect of the cooling rate, stirring rate, temperature and the concentration of ethanol+ water on the MSZWwas studied. It was found that the MSZWof DNTF increased with the increasing cooling rate, decreasing temperature, decreasing stirring rate and decreasing ratio ofwater. And the apparent nucleation order of DNTF in ethanol + water was calculated by the relationship between the cooling rate and the MSZW. (C) 2016 The Chemical Industry and Engineering Society of China, and Chemical Industry Press. All rights reserved.