Highly stable iron on activated carbon catalysts were prepared by chemical activation of dry sewage sludge with iron chloride at different mass ratios (MR = mass of activating agent per unit mass of precursor). The iron content of the resulting catalysts varied between 5.2% and 7.3%. They showed a well developed porosity, with BET surface areas above 800 m(2)/g, despite the high amount of inorganic matter of the sewage sludge used as precursor. TEM images confirmed the presence of iron nanoparticles sized between 3 and 11 nm fairly well dispersed. The catalysts were tested batchwise in the CWPO of antipyrine, a recognized emergent pollutant. Working with 500 mg.L-1 of the catalyst prepared with MR = 3 complete conversion of antipyrine (20 mg.L-1) and almost 70% of TOC reduction were achieved in 1 h with the stoichiometric theoretical amount of H2O2, at pH = 3 and 50 degrees C. This catalyst showed a high stability, in long-term (80 h on stream) continuous experiments where almost negligible iron leaching was observed. (C) 2016 Elsevier B.V. All rights reserved.