A one-step co-deposition (electro induced) process was used to develop graphene oxide/dodecyltriethoxysilane (GO/DTES) coatings with enhanced protection performance, as well as controlled thickness. The scanning electron microscope (SEM), transmission electron microscope (TEM), atomic force microscope (AFM) and X-ray photoelectron spectroscope (XPS) suggested the successful electrochemical synthesis and the inclusion of GO. XPS results and the observation of the strong absorption peak corresponding to COO groups in the diffuse reflectance infrared Fourier transform spectroscope (DRIFT) indicated the covalent bonding and assembly mechanism of OH and COOH groups between the GO and silanol. This revealed the intrinsic reasons for preparing the more compact GO/DTES coatings. Results from the electrochemical impedance spectroscopy (EIS) showed that when the deposition potential and duration were optimized to about -0.8 V and 300 s, respectively, the GO/DTES samples with the maximum average thickness over 400 nm possessed the enhanced corrosion resistance. Analyses on corrosion SEM morphology and energy dispersive X-ray spectroscope (EDX), the long term 3.5% NaCl solution immersion for 480 h, the water contact angle upping to 110 degrees, micro tribology and the adhesion experimental results further proved that there is an improved protection performance of those GO/ DTES samples. The enhanced properties of these GO/DTES coatings can be ascribed to the GO doping and the controlled high thickness, inspiring a practical approach towards the fabrication of GO-based protection materials. (C) 2017 Elsevier B.V. All rights reserved.