In this work, plasma-catalytic oxidation of low concentration ethyl acetate (100 ppm) over La1-xCexCoO3+delta (X = 0, 0.05, 0.1, 0.3 and 0.5) perovskite catalysts was carried out in a coaxial dielectric barrier discharge (DBD) reactor. The effects of Ce-doping on the removal of ethyl acetate and COx (x =1 and 2) selectivity in the plasma-catalytic oxidation process were investigated as a function of specific energy density (SED). Compared to the plasma reaction without a catalyst, the presence of the LaCoO3 catalyst in the plasma enhanced the removal of ethyl acetate and COx selectivity. The use of the Ce-doped catalysts further enhanced the performance of the plasma-catalytic oxidation process. The highest removal efficiency of ethyl acetate (100%) and COx selectivity (91.8%) were achieved in the plasma-catalytic oxidation of ethyl acetate over the La0.9Ce0.1CoO3+delta catalyst at a SED of 558 J L-1. The interactions between Ce and LaCoO3 resulted in an increased specific surface area (by 17.1%-68.6%) and a reduced crystallite size (by 13.5%-68.2%) of the Ce-doped LaCo03 catalysts compared to pure LaCoO3, which favours the oxidation of ethyl acetate in the plasma process. Compared to the LaCoO3 catalyst, the Ce-doped perovskite catalysts showed higher content (maximum 54.9%) of surface adsorbed oxygen (Clads) and better reducibility, both of which significantly contributed to the enhanced oxidation of ethyl acetate and intermediates in the plasma-assisted surface reactions. The coupling of plasma with the Ce-doped catalysts also reduced the formation of by-products including NO2 and N-2 O. The possible reaction pathways involved in the plasma oxidation process have been discussed. (C) 2017 Elsevier B.V. All rights reserved.