화학공학소재연구정보센터
Journal of Industrial and Engineering Chemistry, Vol.52, 82-88, August, 2017
Synthesis of acetic acid-[(hydrazinylthioxomethyl)thio]-sodium and its application on the flotation separation of molybdenite from galena
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A novel organic compound acetic acid-[(hydrazinylthioxomethyl)thio]-sodium was synthesized and characterized. The flotation performance and adsorption mechanism of AHS to galena were investigated by micro, bench flotation tests, UV spectra, zeta potential, FTIR and XPS measurements. The results demonstrated that AHS exhibited superior depressing power to galena and could be used as selective depressant for flotation separation of molybdenite from galena. The results of UV spectra, FTIR, zeta potential and XPS measurements demonstrated that AHS chemisorb on galena surface by forming fivemembered cheat ring with releasing of H ions. Therefore, the possible adsorption mode of AHS on galena surface was recommended.
  1. liu Y, Zhang YF, Chen FF, Zhang Y, Hydrometallurgy, 129-130, 30 (2014)
  2. Choi YY, Kim SB, Kim BS, Lee HI, Patent, US 8163258B2, 2012.
  3. Miller JD, Ye Y, Jang WH, Patent, US 5068028.
  4. Pestryak I, Morozov V, Baatarhuu J, Int. J. Min. Sci. Technol., 23, 41 (2013)
  5. Shugarman AL, Calif SA, Patent, US 4704260, 1987.
  6. Padila R, Opazo C, Ruiz MC, Metall. Mater. Trans. B-Proc. Metall. Mater. Proc. Sci., 46B, 30 (2015)
  7. Shi L, Li J, Xie JH, Min. Metall. Eng., 29, 63 (2009)
  8. Abdollahi H, Shafaei SZ, Noaparast M, Manafi Z, Niemela SI, Tuovinen OH, Int. J. Miner. Process. (128) (2014) 25.
  9. Zamani MAA, Vaghar R, Oliazadeh M, Int. J. Miner. Process., 81(2), 105 (2006)
  10. Romano P, Blazquez ML, Ballester A, Gonzalez F, Alguacil FJ, Miner. Eng., 14(9), 987 (2001)
  11. Hadi A, Zahra M, Ziaedin SS, Mohammad N, Navid MM, Int. J. Min. Sci. Technol., 23, 827 (2013)
  12. Choi J, Lee E, Choi SQ, Lee S, Han Y, Kim H, Chem. Eng. J., 285, 207 (2016)
  13. Malhotra D, Rowe RM, Bhasin AK, Recovery of molybdenite. Patent, US 4606817, 1986.
  14. Peterson JA, Falls N, Saran MS, Wisnouskas JS, Patent, US 4575419, 1986.
  15. Li MY, Wei DZ, Liu Q, Liu WB, Zheng JM, Sun HJ, Miner. Eng., 83, 217 (2015)
  16. Mu YF, Peng YJ, Lauten RA, Miner. Eng., 96-97, 143 (2016)
  17. Laskowski JS, Liu Q, O'Connor CT, Int. J. Miner. Process., 84(1-4), 59 (2007)
  18. Sarquis PE, Menendez-Aguado JM, Mahamud MM, Dizoba R, J. Clean. Prod., 84, 723 (2014)
  19. Liu Q, Laskowski JS, Int. J. Miner. Process., 27, 147 (1989)
  20. Raju GB, Holmgren A, Forsling W, J. Colloid Interface Sci., 193(2), 215 (1997)
  21. Castro S, Laskowski JS, Miner. Eng., 74, 13 (2015)
  22. Braga PFA, Chaves AP, Luz AB, Franca SCA, Int. J. Min. Sci. Technol, 127, 23 (2014)
  23. Beaussart A, Parkinson L, Mierczynska-Vasilev A, Beattie DA, J. Colloid Interface Sci., 368, 608 (2012)
  24. Jiang YR, Zhou LH, Xie YL, Zhu JG, Min. Metall. Eng, 21, 33 (2001)
  25. Chen JH, Lan LH, Liao XJ, Trans. Nonferrous Met. Soc. China, 23, 824 (2013)
  26. Yin ZG, Sun W, Hu YH, Zhai JH, Guan QJ, Sep. Purif. Technol., 173, 9 (2017)
  27. Liu Y, Liu Q, Miner. Eng., 17(7-8), 865 (2004)
  28. Piao ZJ, Wei DZ, Liu ZL, Trans. Nonferrous Met. Soc. China, 24, 3343 (2014)
  29. Li MY, Wei DZ, Shen YB, Liu WG, Gao SL, Liang GQ, Trans. Nonferrous Met. Soc. China, 25, 3126 (2015)
  30. Ali MA, Tarafdar MTH, J. Inorg. Nucl. Chem., 39, 1785 (1977)
  31. Wise CF, Liu D, Mayer KJ, Crossland PM, Hartley CL, McNamara WR, Dalton Trans., 44, 14265 (2015)
  32. Alaghaz ANAA, Zayed ME, Alharbi SA, J. Mol. Struct., 1083, 430 (2015)
  33. Bersa P, Kim CH, Seok S, Inorg. Chim. Acta., 362, 2603 (2009)
  34. Chew KB, Tarafder MTH, Crouse KA, Ali AM, Yamin RM, Fun HK, Polyhedron, 23, 1385 (2004)
  35. Yin ZG, Sun W, Hu YH, Zhang CH, Guan QJ, Liu RQ, Chen P, Tian MJ, Sep. Purif. Technol., 179, 248 (2017)
  36. Abou-Hussein AA, Linert W, Spectroc. Acta Pt. A-Molec. Biomolec. Spectr., 117, 763 (2014)
  37. Vergouw JM, Difeo A, Xu Z, Finch JA, Miner. Eng., 11(2), 159 (1998)
  38. Qin WQ, Wang XJ, Ma LY, Jiao F, Liu RZ, Yang CR, Gao K, Miner. Eng., 74, 99 (2015)
  39. Ikumapayi F, Makitalo M, Johansson B, Rao KH, Miner. Eng., 39, 77 (2012)
  40. Mikhlin Y, Karacharov A, Tomashevich V, Shchukarev A, Vacuum, 125, 98 (2016)
  41. Laajalehto K, Smart RSC, Ralston J, Suoninen E, Appl. Surf. Sci., 64, 29 (1993)
  42. Nowak P, Laajalehto K, Kartio I, Colloids Surf. A: Physicochem. Eng. Asp., 161, 447 (2000)
  43. Giudici GD, Rossi A, Fanfani L, Lattanzi P, Geochim. Cosmochim. Acta, 69, 2321 (2005)
  44. Ikumapayi F, Makitalo M, Johansson B, Rao KH, Miner. Eng., 39, 77 (2012)
  45. Tampouris K, Coco S, Yannopoulos A, Koinis S, Polyhedron, 26, 4269 (2007)
  46. Bera P, Kim CH, Seok S II, Polyhedron, 27, 3433 (2008)
  47. Ma X, Hu Y, Zhong H, Wang S, Liu GY, Zhao G, Appl. Surf. Sci., 365, 342 (2016)
  48. Mikhlin YL, Karacharov AA, Likhatski MN, Int. J. Miner. Process., 144, 81 (2015)
  49. Lara RH, Briones R, Monroy MG, Mullet M, Humbert B, Dossot M, Naja GM, Cruz R, Sci. Total Environ., 409, 3971 (2011)
  50. He Z, Liu G, Yang X, Liu W, J. Ind. Eng. Chem., 37, 107 (2016)