화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.52, 66-72, August, 2017
DOI10.1016/j.jiec.2017.03.025  Export Citation
Diffusive transport through surface functionalized nanoporous alumina membranes by atomic layer deposition of metal oxides
V. Vega1, 2, †, L. Gelde3, A.S. González4, V.M. Prida4, B. Hernando4, and J. Benavente3
  • 1Laboratorio de Membranas Nanoporosas, Servicios Científico-Técnicos, Universidad de Oviedo, 33006 Oviedo, Spain
  • 2Departamento de Física, Facultad de Ciencias, Universidad de Oviedo, 33007 Oviedo, Spain
  • 3Departamento de Física Aplicada I, Facultad de Ciencias, Universidad de Málaga, 29071 Málaga, Spain
  • 4Departamento de Física, Facultad de Ciencias, Universidad de Oviedo, 33007 Oviedo, Spain, Korea
E-mail:
Changes associated to surface functionalization of nanoporous alumina membranes by atomic layer deposition (ALD) of metal oxides (Al2O3, SiO2, TiO2, Fe2O3, ZnO) are presented. ALD modification of the alumina membranes reveals a reduction up to 25.35% in porosity, and confirms the presence of the metal oxide layer coating the pores. Its effect on the membrane permselectivity and other characteristic transport parameters was determined from membrane potential measurements, being correlated with changes in morphology and physic.chemical characteristics of the alumina membranes. According to our results, ALD provides a straight-forward and efficient method to adjust membrane performance for specific applications.
Keywords:Nanoporous alumina membranes;ALD surface coating;SEM analysis;Membrane potentials;Permselectivity
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