D-Limonene as a green bio-solvent for dispersive liquid.liquid microextraction of b-cyclodextrin followed by spectrophotometric determination

Nahid Pourreza; Tina Naghdi

Journal of Industrial and Engineering Chemistry, Vol.51, 71-76, July, 2017

DOI10.1016/j.jiec.2017.02.016 Export Citation

D-Limonene as a green bio-solvent for dispersive liquid.liquid microextraction of b-cyclodextrin followed by spectrophotometric determination

Nahid Pourreza^†, and Tina Naghdi

Department of Chemistry, Faculty of Science, Shahid Chamran University of Ahvaz, Ahvaz, Iran

E-mail:

In this paper D-limonene and b-carotene are introduced as two natural products in a dispersive liquid. liquid microextraction (DLLME) method for spectrophotometric determination of β-cyclodextrin (β-CD). Dissolved β-carotene in D-limonene exhibits strong absorption exhibits strong absorption intensity after performing. The absorption intensity of the extracted phase is increased in the presence of β-CD due to its interaction (complex formation) with β-carotene. This increase in the absorbance of the extracted phase is related to the β-CD concentration and was utilized as an analytical signal for determination of β-CD. The effect of chemical variables such as pH of the sample solution, nature and volume of dispersive solvent, volume of extraction solvent and extraction time on the DLLME method was studied and optimum conditions were established. The calibration curve was linear in the range of 1x10-4. 6x10-3 mol L-1 (r = 0.9956) with a limit of detection 4x10-5 mol L-1. The relative standard deviation for eight replicate determinations of 1x10-3 mol L-1 and 5x10-3 mol L-1 of β-CD was 1.82% and 0.88% respectively. The proposed method was successfully applied to the determination of β-CD in spiked water and pharmaceutical samples and good recoveries in the range of 94.2-108.0% were obtained.

Keywords:Dispersive liquid.liquid microextraction;β-Cyclodextrine;D-Limonene;Green solvent;Spectrophotometric

[References]

Zaibunnisa AH, Aini Marhanna MNA, Ainun Atirah M, Int. Food Res. J., 18, 1061 (2011)
Afkhami A, Khalafi L, Anal. Chim. Acta, 569, 267 (2006)
Hergert LA, Escandar GM, Talanta, 60, 235 (2003)
Perchyonok VT, Curr. Org. Chem., 16, 2365 (2012)
Del Valle EMM, Process Biochem., 39(9), 1033 (2004)
Stella VJ, He Q, Toxicol. Pathol., 36, 30 (2008)
Kondo H, Nakatani H, Hiromi K, Carbohydr. Res., 52, 1 (1976)
Reeuwijk HJEM, Irth H, Tjaden UR, Merkus FWHM, Van der Greef J, J. Chromatogr., 614, 95 (1993)
Jadhay GP, Roy T, Deshpande AD, More HN, Indian Drugs, 36, 506 (1999)
Frijlink HW, Visser J, Drenth BFH, J. Chromatog., 415, 325 (1987)
Hokse H, Carbohydr. Res., 114, 303 (1983)
Jun G, Yong ZH, Jinghao P, Microchem. J., 60, 26 (1998)
Higuti IH, da Silva PA, Papp J, Eiroz Okiyama VM, Andrade EA, Abreu Marcondes A, Nascimento AJ, Braz. Arch. Biol. Technol., 47(6), 837 (2004)
Pourreza N, Naghdi T, J. Ind. Eng. Chem., 20(5), 3502 (2014)
Anthemidis AN, Ioannou KG, Talanta, 80, 413 (2009)
Andruch V, Kocurova L, Balogh IS, Skrlikova J, Microchem. J., 102, 1 (2012)
Rastegarzadeh S, Pourreza N, LarkI A, Spectroc. Acta Pt. A-Molec. Biomolec. Spectr., 114, 46 (2013)
Ebrahimpour B, Yamini Y, Seidi S, Tajik M, Anal. Chim. Acta, 885, 98 (2015)
Pourreza N, Rastegarzadeh S, Larki A, Talanta, 134, 24 (2015)
Al-Saidi HM, Emara AAA, J. Saudi Chem. Soc., 18, 745 (2014)
Kocurova L, Balogh IS, Sandrejova J, Andruch V, Microchem. J., 102, 11 (2012)
Ma J, Lu W, Chen L, Curr. Anal. Chem., 8, 78 (2012)
Wen YY, Li JH, Zhang WW, Chen LX, Electrophoresis, 32(16), 2131 (2011)
Li J, Lu W, Ma J, Chen L, Microchim. Acta, 175, 301 (2011)
Liu JY, Lu WH, Liu HT, Wu XQ, Li JH, Chen LX, Electrophoresis, 37(19), 2502 (2016)
Chemat S, Tomao V, Chemat F, Limonene as green solvent for extraction of natural products, Green Solvents I: Properties and Applications in Chemistry, (2012) , pp. 175.
Virot M, Tomao V, Ginies C, Chemat F, Chromatographia, 68, 311 (2008)
Mele A, Mendichi R, Selva A, Carbohydr. Res., 310, 261 (1998)
Arikan S, Rodway RG, Anim. Reprod. Sci., 64, 149 (2000)
Matloob AH, Mourtas S, Klepetsanis P, Antimisiaris SG, Int. J. Pharm., 476, 108 (2014)
He Y, Fu P, Shen X, Gao H, Micron, 39, 495 (2008)
Siva S, Thulasidhasan J, Rajendiran N, Spectroc. Acta Pt. A-Molec. Biomolec. Spectr., 115, 559 (2013)
Szente L, Mikuni K, Hashimoto H, Szejtli J, J. Incl. Phenom. Macrocycl. Chem., 32, 81 (1998)

[Referenced By]

[1] Zaibunnisa AH, Aini Marhanna MNA, Ainun Atirah M, Int. Food Res. J., 18, 1061 (2011)

[2] Afkhami A, Khalafi L, Anal. Chim. Acta, 569, 267 (2006)

[3] Hergert LA, Escandar GM, Talanta, 60, 235 (2003)

[4] Perchyonok VT, Curr. Org. Chem., 16, 2365 (2012)

[5] Del Valle EMM, Process Biochem., 39(9), 1033 (2004)

[6] Stella VJ, He Q, Toxicol. Pathol., 36, 30 (2008)

[7] Kondo H, Nakatani H, Hiromi K, Carbohydr. Res., 52, 1 (1976)

[8] Reeuwijk HJEM, Irth H, Tjaden UR, Merkus FWHM, Van der Greef J, J. Chromatogr., 614, 95 (1993)

[9] Jadhay GP, Roy T, Deshpande AD, More HN, Indian Drugs, 36, 506 (1999)

[10] Frijlink HW, Visser J, Drenth BFH, J. Chromatog., 415, 325 (1987)

[11] Hokse H, Carbohydr. Res., 114, 303 (1983)

[12] Jun G, Yong ZH, Jinghao P, Microchem. J., 60, 26 (1998)

[13] Higuti IH, da Silva PA, Papp J, Eiroz Okiyama VM, Andrade EA, Abreu Marcondes A, Nascimento AJ, Braz. Arch. Biol. Technol., 47(6), 837 (2004)

[14] Pourreza N, Naghdi T, J. Ind. Eng. Chem., 20(5), 3502 (2014)

[15] Anthemidis AN, Ioannou KG, Talanta, 80, 413 (2009)

[16] Andruch V, Kocurova L, Balogh IS, Skrlikova J, Microchem. J., 102, 1 (2012)

[17] Rastegarzadeh S, Pourreza N, LarkI A, Spectroc. Acta Pt. A-Molec. Biomolec. Spectr., 114, 46 (2013)

[18] Ebrahimpour B, Yamini Y, Seidi S, Tajik M, Anal. Chim. Acta, 885, 98 (2015)

[19] Pourreza N, Rastegarzadeh S, Larki A, Talanta, 134, 24 (2015)

[20] Al-Saidi HM, Emara AAA, J. Saudi Chem. Soc., 18, 745 (2014)

[21] Kocurova L, Balogh IS, Sandrejova J, Andruch V, Microchem. J., 102, 11 (2012)

[22] Ma J, Lu W, Chen L, Curr. Anal. Chem., 8, 78 (2012)

[23] Wen YY, Li JH, Zhang WW, Chen LX, Electrophoresis, 32(16), 2131 (2011)

[24] Li J, Lu W, Ma J, Chen L, Microchim. Acta, 175, 301 (2011)

[25] Liu JY, Lu WH, Liu HT, Wu XQ, Li JH, Chen LX, Electrophoresis, 37(19), 2502 (2016)

[26] Chemat S, Tomao V, Chemat F, Limonene as green solvent for extraction of natural products, Green Solvents I: Properties and Applications in Chemistry, (2012) , pp. 175.

[27] Virot M, Tomao V, Ginies C, Chemat F, Chromatographia, 68, 311 (2008)

[28] Mele A, Mendichi R, Selva A, Carbohydr. Res., 310, 261 (1998)

[29] Arikan S, Rodway RG, Anim. Reprod. Sci., 64, 149 (2000)

[30] Matloob AH, Mourtas S, Klepetsanis P, Antimisiaris SG, Int. J. Pharm., 476, 108 (2014)

[31] He Y, Fu P, Shen X, Gao H, Micron, 39, 495 (2008)

[32] Siva S, Thulasidhasan J, Rajendiran N, Spectroc. Acta Pt. A-Molec. Biomolec. Spectr., 115, 559 (2013)

[33] Szente L, Mikuni K, Hashimoto H, Szejtli J, J. Incl. Phenom. Macrocycl. Chem., 32, 81 (1998)