화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Korean Journal of Chemical Engineering, Vol.34, No.6, 1813-1821, June, 2017
DOI10.1007/s11814-017-0049-6  Export Citation
Developing thin film heterogeneous ion exchange membrane modified by 2-acrylamido-2-methylpropanesulfonic acid hydrogel-co-super activated carbon nanoparticles coating layer
Mahsa Nemati, Sayed Mohsen Hosseini†, and Meisam Shabanian1
  • Department of Chemical Engineering, Faculty of Engineering, Arak University, Arak 38156-8-8349, Iran
  • 1Faculty of Chemistry and Petrochemical Engineering, Standard Research Institute, Karaj 31745-139, Iran
E-mail:
Highly selective cation exchange membranes were prepared by coating a thin 2-acrylamido-2-methylpropanesulfonic acid based hydrogel layer and super activated carbon nanoparticles-co-hydrogel layer on polyvinyl chloride based cation exchange membranes. FTIR analysis proved hydrogel formation on membrane surface successfully. Scanning electron microscopy images and swelling ratio measurement were used to study the effect of super activated carbon nanoparticles on properties of formed hydrogel. The surface morphology, surface hydrophilicity and roughness analysis were also used in membrane characterization. Membrane water content was increased by formation of modified layer on the membranes surface. Modified membranes showed a remarkable improvement in potential, permselectivity and transport number compared to pristine type. Membrane ionic flux and permeability were improved initially by using modifier layer on membrane surface, and then showed decreasing trend at high nanoparticles loading ratios in hydrogel layer. Modified membranes showed lower electrical resistance compared to unmodified membrane.
Keywords:Cation Exchange;Thin Film;Coating Layer;Hydrogel;Super Activated Carbon Nanoparticles
  1. Hegab HM, Wimalasiri Y, Ginic-Markovic M, Zou L, Desalination, 365, 99 (2015)
  2. El-Din LAN, El-Gendi A, Ismail N, Abed KA, Ahmed AI, J. Ind. Eng. Chem., 26, 259 (2015)
  3. Zou L, Vidalis I, Steele D, Michelmore A, Low SP, Verberk JQJC, J. Membr. Sci., 369(1-2), 420 (2011)
  4. Yin J, Deng BL, J. Membr. Sci., 479, 256 (2015)
  5. Farrokhzad H, Kikhavani T, Monnaie F, Ashrafizadeh SN, Koeckelberghs G, Van Gerven T, Van der Bruggen B, J. Membr. Sci., 474, 167 (2015)
  6. Zuo XT, Shi WX, Tian ZD, Yu SL, Wang S, He JJ, Desalination, 311, 150 (2013)
  7. Zuo XT, Yu SL, Shi WX, Desalination, 290, 83 (2012)
  8. Reig M, Farrokhzad H, Van der Bruggen B, Gibert O, Cortina JL, Desalination, 375, 1 (2015)
  9. Farrokhzad H, Darvishmanesh S, Genduso G, Van Gerven T, Van der Bruggen B, Electrochim. Acta, 158, 64 (2015)
  10. Mir FQ, Shukla A, Desalination, 372, 1 (2015)
  11. Galama AH, Hoog NA, Yntema DR, Desalination, 380, 1 (2016)
  12. Mikhaylin S, Nikonenko V, Pismenskaya N, Pourcelly G, Choi S, Kwon HJ, Han J, Bazinet L, Desalination, 393, 102 (2016)
  13. Hosseini S, Hamidi A, Moghadassi A, Parvizian F, Madaeni SS, Korean J. Chem. Eng., 32(9), 1827 (2015)
  14. Habibi S, Nematollahzadeh A, Mousavi SA, Chem. Eng. J., 267, 306 (2015)
  15. Hosseini SM, Nemati M, Jeddi F, Salehi E, Khodabakhshi AR, Madaeni SS, Desalination, 359, 167 (2015)
  16. Hosseini SM, Hamidi A, Moghadassi A, Madaeni SS, Korean J. Chem. Eng., 32(3), 429 (2015)
  17. Nemati M, Hosseini SM, Bagheripour E, Madaeni SS, Korean J. Chem. Eng., 33(3), 1037 (2016)
  18. Yu SC, Lu ZH, Chen ZH, Liu XS, Liu MH, Gao CJ, J. Membr. Sci., 371(1-2), 293 (2011)
  19. Shafi HZ, Khan Z, Yang R, Gleason KK, Desalination, 362, 93 (2015)
  20. Guo HF, Ulbricht M, J. Membr. Sci., 349(1-2), 312 (2010)
  21. Hosseini SM, Madaeni SS, Khodabakhshi AR, Zendehnam A, J. Membr. Sci., 365(1-2), 438 (2010)
  22. Daraei P, Madaeni SS, Ghaemi N, Monfared HA, Khadivi MA, Sep. Purif. Technol., 104, 32 (2013)
  23. Choi YJ, Song JH, Kang MS, Seo BK, Electrochim. Acta, 180, 71 (2015)
  24. Moochani M, Moghadassi A, Hosseini SM, Bagheripour E, Parvizian F, Korean J. Chem. Eng., 33(9), 2674 (2016)
  25. Choi YJ, Kang MS, Kim SH, Cho J, Moon SH, J. Membr. Sci., 223(1-2), 201 (2003)
  26. Peng N, Wang Y, Ye Q, Liang L, An Y, Li Q, Chang C, Carbohydr. Polym., 137, 59 (2016)
  27. Du Z, Hu Y, Gu X, Hu M, Wang C, Colloids Surf. A: Physicochem. Eng. Asp., 489, 1 (2016)
  28. Ma Y, Bai T, Wang F, Mater. Sci. Eng. C., 59, 948 (2016)
  29. Alshehri SM, Aldalbahi A, Al-hajji AB, Chaudhary AA, Panhuis M, Alhokbany N, Ahamad T, Carbohydr. Polym., 138, 229 (2016)
  30. Guilherme MR, Reis AV, Paulino AT, Fajardo AR, Muniz EC, Tambourgi EB, J. Appl. Polym. Sci., 105(5), 2903 (2007)
  31. Zhang CM, Geng Z, Cai M, Zhang J, Liu XP, Xin HF, Ma JX, Int. J. Hydrog. Energy, 38(22), 9243 (2013)
  32. Kim BH, Kim CH, Lee DG, J. Electroanal. Chem., 760, 64 (2016)
  33. Zhou L, Zhou YP, Sun Y, Int. J. Hydrog. Energy, 29(5), 475 (2004)
  34. Mukherjee R, De S, Sep. Purif. Technol., 157, 229 (2016)
  35. Skouteris G, Saroj D, Melidis P, Hai FI, Ouki S, Bioresour. Technol., 185, 399 (2015)
  36. Bonvin F, Jost L, Randin L, Bonvin E, Kohn T, Water Res., 90, 90 (2016)
  37. Georgi A, Schierz A, Mackenzie K, Kopinke FD, J. Contam. Hydrol., 179, 76 (2015)
  38. Hegab HM, Wimalasiri Y, Ginic-Markovic M, Zou L, Desalination, 365, 99 (2015)
  39. Sata T, Ion Exchange Membranes: Preparation, Characterization, Modification and Application, The Royal Society of Chemistry, Cambridge Publications, United Kingdom (2004).
  40. Nagarale RK, Gohil GS, Shahi VK, Rangarajan R, Colloids Surf. A: Physicochem. Eng. Asp., 251, 133 (2004)
  41. Li XF, Wang Z, Lu H, Zhao CJ, Na H, Zhao C, J. Membr. Sci., 254(1-2), 147 (2005)
  42. Tanaka Y, Ion Exchange Membranes: Fundamentals and Applications, Elsevier, Netherlands, 12 (2007).
  43. Nagarale RK, Shahi VK, Thampy SK, Rangarajan R, React. Funct. Polym., 61(1), 131 (2004)
  44. Gohil GS, Binsu VV, Shahi VK, J. Membr. Sci., 280(1-2), 210 (2006)
  45. Kerres J, Cui W, Disson R, Neubrand W, J. Membr. Sci., 139(2), 211 (1998)
  46. Shahi VK, Thampy SK, Rangarajan R, J. Membr. Sci., 158(1-2), 77 (1999)
  47. Nagarale RK, Shahi VK, Rangarajan R, J. Membr. Sci., 248(1-2), 37 (2005)
  48. Hosseini SM, Gholami A, Koranian P, Nemati M, Madaeni SS, Moghadassi AR, J. Taiwan Inst. Chem. Eng., 45, 1241 (2014)
  49. Hosseini SM, Madaeni SS, Heidari AR, Khodabakhshi AR, Desalination, 285, 253 (2012)
  50. Limparyoon N, Seetapan N, Kiatkamjornwong S, Polym. Degrad. Stabil., 96, 1054 (2011)
  51. Hebeish A, Hashem M, El-Hady MMA, Sharaf S, Carbohydr. Polym., 92, 407 (2013)
  52. McCloskey BD, Park HB, Ju H, Rowe BW, Miller DJ, Freeman BD, J. Membr. Sci., 413, 82 (2012)