마이크로웨이브를 이용한 그래프트된 전분의 합성과 특성분석 및 응용

Yangshuo Liu; Teng Luo; Ming Li; Fucheng Yu

Polymer(Korea), Vol.41, No.3, 372-377, May, 2017

DOI10.7317/pk.2017.41.3.372 Export Citation

마이크로웨이브를 이용한 그래프트된 전분의 합성과 특성분석 및 응용

Synthesis, Characterization and Application of Grafted Starch Prepared with Microwave-assistance

Yangshuo Liu, Teng Luo, Ming Li, and Fucheng Yu¹

College of Chemistry and Chemical Engineering, Wuhan Textile University, Wuhan 430074, China
¹School of Material Science and Engineering, Lanzhou University of Technology, Lanzhou 730050, China

Butyl acrylate grafted starch (St-g-BA) was made by the method of microwave-assisted synthesis, involving the combination of microwave irradiation and a chemical free radical initiator (H2O2-Fe2+) to initiate the grafting reaction. The optimal conditions for the graft copolymerization with respect to reaction microwave power, exposure time and type of initiator were investigated. Under the optimal conditions, the percent grafting and grafting efficiency were 26.2% and 85.9%, respectively. The grafted starch was characterized by using Fourier transform infrared spectroscopy (FTIR) and scanning electron microscopy (SEM). The St-g-BA exhibited good tensile strength, elongation at break and abrasion resistance. Therefore, it is suggested this biomaterial could be used in various industrial applications such as textile sizing and food packaging.

Keywords:microwave irradiation;graft;starch;butyl acrylate;textile sizing

[References]

Reddy N, Chen LH, Zhang Y, Yang YQ, J. Clean Prod., 65, 561 (2014)
Li ML, Zhu ZF, Pan X, Starch-Starke, 63, 683 (2011)
Mostafa KHM, EI-Sanabary AA, Polym. Degrad. Stabil., 55, 181 (1997)
Zhao Y, Xu HL, Mu BN, Xu L, Hogan R, Yang YQ, Ind. Crop. Prod., 89, 455 (2016)
Mostafa KHM, Morsy MS, Starch-Starke, 56, 254 (2004)
Hebeish A, Higazy A, El-Shafei A, Sharaf S, Carbohydr. Polym., 79, 60 (2010)
Mostafa KHM, Morsy MS, Polym. Int., 53, 885 (2004)
Zhang B, Zhou YY, J. Donghua University, 6, 86 (2005)
Hebeish A, Abdel-Rahman A, El-Hilw Z, Hashem M, Starch-Starke, 57, 616 (2005)
Li XL, Zhu ZF, Pan X, Starch-Starke, 63, 683 (2011)
Jeong JO, Jeong SI, Shin YM, Park JS, Gwon HJ, An SJ, Huh JB, Shin H, Lim YM, Polym. Korea, 39(3), 418 (2015)
Perreux L, Loupy A, in Microwaves in Organic Synthesis, 2nd ed., Loupy A, Editor, Wiley-VCH, Weinheim, Chap. 4, p 134 (2006).
Mishra S, Sen G, Int. J. Biol. Macromol., 48, 688 (2011)
Sen G, Mishra S, Jha U, Pal S, Int. J. Biol. Macromol., 47, 164 (2010)
Singh V, Tiwari A, Tripathi DN, Sanghi R, Polymer, 47(1), 254 (2006)
Mishra S, Mukul A, Sen G, Jha U, Int. J. Biol. Macromol., 48, 106 (2011)
Singh V, Maurya S, Int. J. Biol. Macromol., 47, 348 (2010)
Pal S, Ghorai S, Dash MK, Ghosh S, Udayabhanu G, J. Hazard. Mater., 192(3), 1580 (2011)
Pal S, Sen G, Ghosh S, Singh RP, Carbohydr. Polym., 87, 336 (2012)
Rani P, Sen G, Mishra S, Jha U, Carbohydr. Polym., 89, 275 (2012)
Singh V, Tiwari A, Carbohydr. Res., 343, 151 (2008)
Soetaredjo FE, Ismadji S, Huynh LH, Kasim NS, Tran-Thi NY, Ayucitra A, Ju YH, Starch-Starke, 64, 590 (2012)
Shogren RL, Biswas A, Carbohydr. Polym., 64, 16 (2006)
Singh V, Tiwari A, Tripathi DN, Sainghi R, Biomacromolecules, 6(1), 453 (2005)
Galema SA, Chem. Soc. Rev., 26, 233 (1997)
Xia DC, Zhu ZF, Bian HM, Liu ZJ, J. Donghua University, Natural Science, 36, 649 (2010)
Zhu ZF, Li ML, Jin EQ, J. Appl. Polym. Sci., 112(5), 2822 (2009)

[1] Reddy N, Chen LH, Zhang Y, Yang YQ, J. Clean Prod., 65, 561 (2014)

[2] Li ML, Zhu ZF, Pan X, Starch-Starke, 63, 683 (2011)

[3] Mostafa KHM, EI-Sanabary AA, Polym. Degrad. Stabil., 55, 181 (1997)

[4] Zhao Y, Xu HL, Mu BN, Xu L, Hogan R, Yang YQ, Ind. Crop. Prod., 89, 455 (2016)

[5] Mostafa KHM, Morsy MS, Starch-Starke, 56, 254 (2004)

[6] Hebeish A, Higazy A, El-Shafei A, Sharaf S, Carbohydr. Polym., 79, 60 (2010)

[7] Mostafa KHM, Morsy MS, Polym. Int., 53, 885 (2004)

[8] Zhang B, Zhou YY, J. Donghua University, 6, 86 (2005)

[9] Hebeish A, Abdel-Rahman A, El-Hilw Z, Hashem M, Starch-Starke, 57, 616 (2005)

[10] Li XL, Zhu ZF, Pan X, Starch-Starke, 63, 683 (2011)

[11] Jeong JO, Jeong SI, Shin YM, Park JS, Gwon HJ, An SJ, Huh JB, Shin H, Lim YM, Polym. Korea, 39(3), 418 (2015)

[12] Perreux L, Loupy A, in Microwaves in Organic Synthesis, 2nd ed., Loupy A, Editor, Wiley-VCH, Weinheim, Chap. 4, p 134 (2006).

[13] Mishra S, Sen G, Int. J. Biol. Macromol., 48, 688 (2011)

[14] Sen G, Mishra S, Jha U, Pal S, Int. J. Biol. Macromol., 47, 164 (2010)

[15] Singh V, Tiwari A, Tripathi DN, Sanghi R, Polymer, 47(1), 254 (2006)

[16] Mishra S, Mukul A, Sen G, Jha U, Int. J. Biol. Macromol., 48, 106 (2011)

[17] Singh V, Maurya S, Int. J. Biol. Macromol., 47, 348 (2010)

[18] Pal S, Ghorai S, Dash MK, Ghosh S, Udayabhanu G, J. Hazard. Mater., 192(3), 1580 (2011)

[19] Pal S, Sen G, Ghosh S, Singh RP, Carbohydr. Polym., 87, 336 (2012)

[20] Rani P, Sen G, Mishra S, Jha U, Carbohydr. Polym., 89, 275 (2012)

[21] Singh V, Tiwari A, Carbohydr. Res., 343, 151 (2008)

[22] Soetaredjo FE, Ismadji S, Huynh LH, Kasim NS, Tran-Thi NY, Ayucitra A, Ju YH, Starch-Starke, 64, 590 (2012)

[23] Shogren RL, Biswas A, Carbohydr. Polym., 64, 16 (2006)

[24] Singh V, Tiwari A, Tripathi DN, Sainghi R, Biomacromolecules, 6(1), 453 (2005)

[25] Galema SA, Chem. Soc. Rev., 26, 233 (1997)

[26] Xia DC, Zhu ZF, Bian HM, Liu ZJ, J. Donghua University, Natural Science, 36, 649 (2010)

[27] Zhu ZF, Li ML, Jin EQ, J. Appl. Polym. Sci., 112(5), 2822 (2009)