Removal of lead ions was investigated by ethylenediamine, triethylenetetramine and tetraethylenepentamine functionalized polymeric adsorbent. Macroporous acrylonitrile-ethylene glycol-dimethacrylate copolymer beads were synthesized by suspension polymerization as already reported.([17]) The adsorbent was prepared by amination of copolymer synthesized from acrylonitrile-ethylene glycol-dimethacrylate. The adsorption study for removal of lead ions using functionalized poly(AN-EGDMA) copolymer as an adsorbent was carried out at room temperature at various solution concentrations of 0.483-2.4154 mmol/l at pH 4.6. Functionalized polymers were studied by Fourier transform infrared spectroscopy (FTIR). Scanning electron microscope-X-ray energy dispersive spectrometer (SEM-EDAX) was utilized to study an increase in nitrogen content of functionalized polymers.