화학공학소재연구정보센터
International Journal of Hydrogen Energy, Vol.42, No.10, 6950-6964, 2017
Ru-based SOFC anodes: Preparation, performance, and durability
Ru-based solid oxide fuel cell (SOFC) cermet anodes are presented. The preparation conditions of the Ru-based anodes are adjusted by preventing the sublimation of Ru-oxides at elevated temperatures by using an oxidizing atmosphere. SOFC single cells with zirconiaelectrolyte and cathode are prepared, and the electrochemical performance is examined using realistic fuels containing low concentrations of higher hydrocarbons and trace sulfur impurities. The degradation rate is relatively high under simulated high fuel utilization operating conditions. However, under the operational condition near the fuel inlet of SOFC systems, the Ru-based anode satisfies 5000-h durability by using hydrocarbon-containing fuels. While a much higher durability is needed for stationary applications, the cells with the Ru-based anode may be applicable to e.g. automobile applications with hydrocarbon-containing fuels as high internal reforming activity, carbon deposition tolerance, and sulfur impurity tolerance have been verified. (C) 2017 Published by Elsevier Ltd on behalf of Hydrogen Energy Publications LLC.