In the present work, experimental absorption isotherms of hydrogen in LaNi5 at three temperatures have been fitted using a monolayer model treated by statistical physics by means of the grand canonical ensemble. Six parameters of the model are fitted, namely two numbers of absorbed atoms per, site n(1) and n(2), two receptor site densities, N-1M and N-1M and two energetic parameters, P-1 and P-2. The behaviors of these parameters are discussed in relationship with absorption process. Starting from the monolayer model, we determined the absorption energies which are typically ranged between 85 and 101 kJ/mol comparable to usual chemical bond energies. Calculated thermodynamic potentials such as internal energy (E-int) and Gibbs free energy (G) suggested that the absorption processes was exothermic and spontaneous. (C) 2016 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.